Aldol and Michael reactions of nitriles catalyzed by cyclopentadienyl- ruthenium enolate complexes

Synlett

Volumn , Issue 7, 2000, Pages 1016-1018

  Murahashi, Shun Ichi ^a   Take, Kazuhiko ^a   Naota, Takeshi ^a   Takaya, Hikaru ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Aldol reactions; Michael additions; Nitriles; Ruthenium

Indexed keywords

CYCLOPENTADIENE DERIVATIVE; RUTHENIUM COMPLEX;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION;

EID: 0033915260     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (14)

1. Naota, T.; Takaya, H.; Murahashi, S.-I. Chem. Rev. 1998, 98, 2599.
2. (a) Brunner, H. Angew. Chem. Int. Ed. 1999, 38, 1194.
3. (b) Consiglio, G.; Morandini, F. Chem. Rev. 1987, 87, 761.
4. Naota, T.; Taki, H.; Mizuno, M.; Murahashi, S.-I. J. Am. Chem. Soc. 1989, 111, 5954.
5. Murahashi, S.-I.; Naota, T.; Taki, H.; Mizuno, M.; Takaya, H.; Komiya, S.; Mizuho, Y.; Oyasato, N.; Hiraoka, M.; Hirano, M.; Fukuoka, A. J. Am. Chem. Soc. 1995, 117, 12436.
6. Komiya, S.; Mizuho, Y.; Kasuga, N. Chem. Lett. 1991, 2127.
7. 2Ru: C, 68.82; H, 5.15; N, 1.74%. Found: C, 68.77; H, 5.09; N, 1.74%.
8. 3).
9. 3).
10. 3)
11. 3).
12. 6) have been deposited at the Cambridge Crystallographic Data Base (deposition No. CCDC 143822). Copies of the data can be obtained free of charge on application to the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax:+44 1223 336 033; e-mail:deposit@ccdc.cam.ac.uk).
13. -1.
14. 3: C, 66.35; H, 5.10; N, 6.45. Found: C, 66.17; H, 5.03; N, 6.45.