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0342646339
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note
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-1). These results prevent us from attributing with certainty, the difference in PL behavior of the cyclohexane system to a shift in the association equilibrium of Scheme 2.
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34
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0003649923
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Interscience-Publishers: New York, We believe this has little or no effect on the PL response since the pKa values of PrA and AA differ by more than 0.5 pK unit, yet their PL behaviors were found to be similar
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a of PrA, for example, does not vary by more than about 0.1 pK units (see: The Chemistry of Carboxylic Acids and Esters; Patai, S., Ed.; Interscience-Publishers: New York, 1969; p 229). We believe this has little or no effect on the PL response since the pKa values of PrA and AA differ by more than 0.5 pK unit, yet their PL behaviors were found to be similar.
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(1969)
The Chemistry of Carboxylic Acids and Esters
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Patai, S.1
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35
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0001444847
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For the shortest chain (PAA-2K), there are approximately 27 repeat units; the apparent persistence length for PAA in a good solvent, like water, is reported to be less than ∼20 Å, or about six monomer units. See, for example: (a) Muroga, Y.; Noda, I.; Nagasawa, M. Macromolecules 1985, 18, 1576.
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Muroga, Y.1
Noda, I.2
Nagasawa, M.3
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37
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0343516479
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note
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This is a reasonable assumption considering the following: (a) the geometric constraints, on a segmental basis, are similar for a series of polymers differing in molecular weight only, and (b) the binding energy and energetic surface site requirements are similar for each polymer, since the same binding functionality is always present.
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