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For examples: (a) Aluminum alkoxides: Endo, M.; Aida, T.; Inoue, S. Macromolecules 1987, 20, 2982. Dubois, P.; Jérôme, R.; Teyssie, P. Polym. Bull. 1989, 22, 475.
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(c) Rare earth metal alkoxides: Shen, Y.; Shen, Z.; Zhang, Y.; Yao, K. Macromolecules 1996, 29, 8289.
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Shen, Y.1
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(d) Rare earth alkyl complexes: Yamashita, M.; Takemoto, Y.; Ihara, E.; Yasuda, H. Macromolecules 1996, 29, 1798.
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Ihara, E.3
Yasuda, H.4
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0033101849
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3-La, where they could not control the molecular weight and the MWD, and proposed the "nonionic-coordination-insertion mechanism": Deng, X. M.; Yuan, M. L.; Xiong, C. D.; Li, X. H. J. Appl. Polym. Sci. 1999, 71, 1941.
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85064667331
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(a) A comprehensive review: Kobayashi, S. Synlett 1994, 689. See also ref 14.
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17
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0001408869
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2O; see the Supporting Information. Lanthanide salts are notoriously difficult to obtain in an anhydrous state: Aspinall, H. C.; Dwyer, J. L. M.; Greeves, N.; McIver, E. G.; Woolley, J. C. Organometallics 1998, 17, 1884.
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McIver, E.G.4
Woolley, J.C.5
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18
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0343711229
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See the Supporting Information for experimental details
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See the Supporting Information for experimental details.
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19
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0343275684
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3 as an eluent, polystyrene standard)
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3 as an eluent, polystyrene standard).
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20
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0032098261
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A two-step procedure was recently reported: Trollsås, M.; Hedrick, J. L.; Dubois, Ph.; Jérôme, R J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 1345.
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Hedrick, J.L.2
Dubois, Ph.3
Jérôme, R.4
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21
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0343275683
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note
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2O-THF, the mixture is believed to be almost neutral; see refs 5a and 14.
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22
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0021405849
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(a) Okamoto, Y. Polym. Prepr., Am. Chem. Soc., Div. Polym. Chem. 1984, 25 (1), 264.
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Okamoto, Y.1
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23
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0001930696
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(b) Brzezinska, K.; Szymanski, R.; Kubisa, P.; Penczek, S. Makromol. Chem., Rapid Commun. 1986, 7, 1.
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24
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0028197968
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(c) Tokar, R.; Kubisa, P.; Penczek, S.; Dworak, A. Macromolecules 1994, 27, 320.
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26
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0020248181
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(b) Belen'kaya, B. G.; Lyudvig, Ye. B.; Izyumnikov, A. L.; Kul'velis, Yu. I. Polym. Sci. U.S.S.R. 1982, 24, 306.
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Belen'kaya, B.G.1
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27
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0032547286
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Kobayashi, S.; Nagayama, S.; Busujima, T. J. Am. Chem. Soc. 1998, 120, 8287. WERC: water exchange rate constant (exchange rate constants for substitution of inner-sphere water ligand).
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Kobayashi, S.1
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Busujima, T.3
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28
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0343275682
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In one of the leading reports of polymerization of epichlorohydrin via the activated monomer mechanism, Okamoto described ROH as the "molecular weight modifier"; see ref 12a
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In one of the leading reports of polymerization of epichlorohydrin via the activated monomer mechanism, Okamoto described ROH as the "molecular weight modifier"; see ref 12a.
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29
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0342405974
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note
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The "catalytic version" of living polymerization in a coordinated anionic fashion has been well-known as "immortal polymerization", whose mechanism, reactive species, and living polymer termini are in sharp contrast with those of the present system; see ref 2b.
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