Intramolecular stabilization of carbene complexes (CO)4W=C(NRR')Si(aryl)2X (X = H, CMe=CHMe, NEt2) by interaction of the metal center with the silicon substituent X

European Journal of Inorganic Chemistry

Volumn , Issue 8, 2000, Pages 1811-1817

  Schwarz, Matthias ^a   Kickelbick, Guido ^a   Schubert, Ulrich ^a  

^a VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

Agostic interactions; Carbene complexes; Density functional calculations; Silicon; Three center bonds; Tungsten

Indexed keywords

COMPLEXATION; COORDINATION REACTIONS; SILICON; SILICON COMPOUNDS; STABILIZATION; TUNGSTEN;

A-CARBON; AGOSTIC INTERACTIONS; CARBENE COMPLEXES; DENSITY-FUNCTIONAL CALCULATIONS; ELECTRON COMPLEXES; METAL CENTRES; OLEFINIC GROUPS; REACTIVITY STUDIES; SILICON ATOMS; THREE-CENTER BOND;

DENSITY FUNCTIONAL THEORY;

CARBENE; PHENYL GROUP; SILICON DERIVATIVE;

ARTICLE; CALCULATION; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY; ELECTRON; MOLECULAR INTERACTION; PHOTOLYSIS;

EID: 0033859277     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200008)2000:8<1811::aid-ejic1811>3.0.co;2-v     Document Type: Article

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