Syntheses and carbonyliridium complexes of unsymmetrically substituted fluorous trialkylphosphanes: Precision tuning of electronic properties, including insulation of the perfluoroalkyl groups

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2000, Pages 1975-1983

  Alvey, Luke J ^a   Meier, Ralf ^a,b   Soós, Tibor ^a,b   Bernatis, Paul ^a   Gladysz, John A ^a,b  

^a UNIVERSITY OF UTAH   (United States)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Carbonyl complexes; Donor acceptor systems; Fluorine; Iridium; Phosphanes

Indexed keywords

CHLORINE COMPOUNDS; ELECTRONIC PROPERTIES; IRIDIUM; IRIDIUM COMPOUNDS; RHODIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

2-GROUP; CARBONYL COMPLEXES; DONOR-ACCEPTOR SYSTEM; FLUOROUS; MONOTONIC DECREASE; PHOSPHANES; PRECISION TUNING;

FLUORINE;

CARBONYLIRIDIUM DERIVATIVE; FLUORINE; IRIDIUM; METAL DERIVATIVE; PHOSPHANE DERIVATIVE; RHODIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; FLUORINATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033806523     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200009)2000:9<1975::aid-ejic1975>3.0.co;2-m     Document Type: Article

References (44)

1. [1a] I. T. Horváth, J. Rábai, Science 1994, 266, 72-75.
2. [1b] I. T. Horváth, G. Kiss, R. A. Cook, J. E. Bond, P. A. Stevens, J. Rábai, E. J. Mozeleski, J. Am. Chem. Soc. 1998, 120, 3133-3143.
3. [1c] I. T. Horváth, Acc. Chem. Res. 1998, 31, 641-650.
4. Additional review literature since 1999: [2a] E. de Wolf, G. van Koten, B.-J. Deelman, Chem. Soc. Rev. 1999, 28, 37-41.
5. [2b] R. H. Fish, Chem. Eur. J. 1999, 5, 1677-1680.
6. [2c] M. Cavazzini, F. Montanari, G. Pozzi, S. Quici, J. Fluorine Chem. 1999, 94, 183-193.
7. [2d] U. Diederichsen, Nachr. Chem. Tech. Lab. 1999, 47, 805-809.
8. Survey of practical considerations and underlying physical principles: L. P. Barthel-Rosa, J. A. Gladysz, Coord. Chem. Rev. 1999, 190-192, 587-605.
9. [4a] D. Rutherford, J. J. J. Juliette, C. Rocaboy, I. T. Horváth, J. A. Gladysz, Catalysis Today 1998, 42, 381-389.
10. [4b] J. J. J. Juliette, D. Rutherford, I. T. Horváth, J. A. Gladysz, J. Am. Chem. Soc. 1999, 121, 2696-2704.
11. [4c] L. V. Dinh, J. A. Gladysz, Tetrahedron Lett. 1999, 40, 8995-8998.
12. [5a] B. Betzemeier, P. Knochel, Angew. Chem. Int. Ed. Engl. 1997, 36, 2623-2624; Angew. Chem. 1997, 109, 2736-2738.
13. [5a] B. Betzemeier, P. Knochel, Angew. Chem. Int. Ed. Engl. 1997, 36, 2623-2624; Angew. Chem. 1997, 109, 2736-2738.
14. [5b] R. Kling, D. Sinou, G. Pozzi, A. Choplin, F. Quignard, S. Busch, S. Kainz, D. Koch, W. Leitner, Tetrahedron Lett. 1998, 39, 9439-9442.
15. [5c] C. M. Haar, J. Huang, S. P. Nolan, J. L. Petersen, Organometallics 1998, 17, 5018-5024.
16. L. J. Alvey, D. Rutherford, J. J. J. Juliette, J. A. Gladysz, J. Org. Chem. 1998, 63, 6302-6308.
17. M.-A. Guillevic, C. Rocaboy, A. M. Arif, I. T. Horváth, J. A. Gladysz, Organometallics 1998, 17, 707-717.
18. M. Baudler, K. Glinka, Inorg. Synth. 1990, 27, 227-235.
19. J.-M. Vincent, A. Rabion, V. K. Yachandra, R. H. Fish, Angew. Chem. Int. Ed. Engl. 1997, 36, 2346-2349; Angew. Chem. 1997, 109, 2438-2440.
20. J.-M. Vincent, A. Rabion, V. K. Yachandra, R. H. Fish, Angew. Chem. Int. Ed. Engl. 1997, 36, 2346-2349; Angew. Chem. 1997, 109, 2438-2440.
21. Citations of patents that mention this compound: [10a] K. von Werner, Chem. Abstr. 1991, 114, 184774.
22. [10b] K. von Werner, Chem. Abstr. 1985, 103, 214859.
23. [10c] K. von Werner, Chem. Abstr. 1985, 103, 214859.
24. [10d] L. Foulletier, J. P. Lalu, Chem. Abstr. 1978, 88, 169572.
25. [11a] J. O. Metzger, R. Mahler, A. Schmidt, Liebigs Ann. 1996, 693-696.
26. [11b] See also: G. Johansson, V. Percec, G. Ungar, J. P. Zhou, Macromolecules 1996, 29, 646-660.
27. A. Ravve, Principles of Polymer Chemistry, Plenum Press, New York, 1995, p 38.
28. R. Shimizu, T. Fuchikami, Tetrahedron Lett. 1996, 37, 8405-8408.
29. M. Burk, R. H. Crabtree, Inorg. Chem. 1986, 25, 931-932.
30. A. Klose, J. A. Gladysz, Tetrahedron: Asymmetry 1999, 10, 2665-2674.
31. J. Fawcett, E. G. Hope, R. D. W. Kemmitt, D. R. Paige, D. R. Russell, A. M. Stuart, D. J. Cole-Hamilton, M. J. Payne, Chem. Commun. 1997, 1127-1128.
32. J. A. Gladysz, S. P. Nolan, P. R. Rademacher, and coworkers, work in progress.
33. M. Selke, W. L. Karney, S. I. Khan, C. S. Foote, Inorg. Chem. 1995, 34, 5715-5720.
34. M. Schlosser, Angew. Chem. Int. Ed. 1998, 37, 1496-1513; Angew. Chem. 1998, 110, 1538-1556.
35. M. Schlosser, Angew. Chem. Int. Ed. 1998, 37, 1496-1513; Angew. Chem. 1998, 110, 1538-1556.
36. C. Rocaboy, W. Bauer, J. A. Gladysz, Eur. J. Org. Chem. 2000, 2621-2628.
37. C. Li, S. P. Nolan, I. T. Horváth, Organometallics 1998, 17, 452-456.
38. A. J. Deeming, B. L. Shaw, J. Chem. Soc. A 1968, 1887-1889.
39. Recent lead references: [23a] A. Aranyos, D. W. Old, A. Kiyomori, J. P. Wolfe, J. P. Sadighi, S. L. Buchwald, J. Am. Chem. Soc. 1999, 121, 4369-4378.
40. [23b] G. Mann, C. Incarvito, A. L. Rheingold, J. F. Hartwig, J. Am. Chem. Soc. 1999, 121, 3224-3225.
41. Splitting patterns are partially coincidental; chemical shift and coupling constants deduced from visible peaks.
42. 1H decoupling).
43. f8 segments were made on the basis of intensities.
44. f8 carbon atom.