Organophosphorus compounds, 155. 1,2-Additions of organomagnesium halides to phosphaalkynes: Synthesis of 2-phospha-1-vinylmagnesium halides and a novel type of magnesium-phosphorus cage compound

European Journal of Inorganic Chemistry

Volumn , Issue 11, 2000, Pages 2337-2340

  Renner, Jens ^a   Bergsträßer, Uwe ^a   Binger, Paul ^a   Regitz, Manfred ^a  

^a Rheinland Pfälzische Technische Universität Kaiserslautern Landau   (Germany)

Author keywords

Additions; Cage compounds; Grignard reagents; Phosphaalkynes; Phosphavinylmagnesium halides

Indexed keywords

CHLORINE COMPOUNDS; PHOSPHORUS COMPOUNDS; X RAY ANALYSIS;

ADDITION; CAGE COMPOUNDS; GRIGNARD REAGENT; HIGHER YIELD; ORGANOMAGNESIUM; ORGANOPHOSPHORUS COMPOUNDS; PHOSPHAALKYNE; PHOSPHAVINYLMAGNESIUM HALIDE; REGIO-SELECTIVE; STEREO-SELECTIVE; ELEVATED TEMPERATURE;

MAGNESIUM COMPOUNDS;

ALKYNE DERIVATIVE; MAGNESIUM DERIVATIVE; ORGANOMETALLIC COMPOUND; PHOSPHORUS DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; INORGANIC CHEMISTRY; MOLECULAR INTERACTION; SYNTHESIS; X RAY ANALYSIS;

EID: 0033754696     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200011)2000:11<2337::AID-EJIC2337>3.0.CO;2-4     Document Type: Article

References (29)

1. J. Simon, G. J. Reiß, U. Bergsträßen, H. Heydt, M. Regitz, Eur. J. Inorg. Chem. 2000, submitted for publication.
2. D. E. Hibbs, C. Jones, A. F. Richards, J. Chem. Soc., Dalton Trans. 1999, 3531-3532.
3. [3a] P. Binger, B. Biedenbach, C. Krüger, M. Regitz, Angew. Chem. 1987, 99, 798-799;
4. Angew. Chem. Int. Ed. Engl. 1987, 26, 764-765. -
5. [3b] P. Binger, T. Wettling, R. Schneider, F. Zurmühlen, U. Bergsträßer, J. Hofmann, G. Maas, M. Regitz, Angew. Chem. 1991, 103, 208-211;
6. Angew. Chem. Int. Ed. Engl. 1991, 30, 207-210. -
7. [3c] T. Wettling, B. Geißler, R. Schneider, S. Barth, P. Binger, M. Regitz, Angew. Chem. 1992, 104,761-762;
8. Angew. Chem. Int. Ed. Engl. 1992, 31, 758-759. -
9. [3d] B. Geißler, S. Barth, U. Bergsträßer, M. Slany, J. Durkin, P. B. Hitchcock, M. Hofmann, P. Binger, J. F. Nixon, P. von Rague Schleyer, M. Regitz, Angew. Chem. 1995, 107, 485-488;
10. Angew. Chem Int. Ed. Engl. 1995, 34, 484-487.
11. [4a] P. Binger, G. Glaser, B. Gabor, R. Mynott, Angew. Chem. 1995, 107, 114-116;
12. Angew. Chem. Int. Ed. Engl. 1995, 34, 81-83. -
13. [4b] P. Binger, S. Leininger, J. Stannek, B. Gabor, R. Mynott, J. Bruckmann, U. Krüger, Angew. Chem. 1995, 107, 2411-2414;
14. Angew. Chem. Int. Ed. Engl. 1995, 34, 2227-2230. -
15. [4c] P. Binger, S. Leininger, K. Günther, U. Bergsträßer, Chem. Ber./Recueil 1997, 130, 1491-1494.
16. K. Harada, H. Urabe, F. Sato, Tetrahedron Lett. 1995, 36, 3203-3206.
17. We have not presented a detailed discussion of the molecular structure with numerical data because the crystal structure analysis of an analogue of 3a (cyclopentyl in place of isopropyl) has already been published, see. ref.[2]
18. [7a] M. van der Sluis, V. Beverwijk, A. Termaten, E. Gavrilova, F. Bickelhaupt, H. Kooijman, N. Veldman, A. L. Spek, Organometallics 1997, 16, 1144-1152. -
19. [7b] M. van der Sluis, J. B. M. Wit, F. Bickelhaupt, Organometallics 1996, 15, 174-180.
20. Handbook of Grignard Reagents (Eds.: G. S. Silverman, P. E. Rakita), Marcel Dekker Inc., New York, 1996.
21. H. Uhm in ref.[8] p. 117-144.
22. R. Appel, in Multiple Bonds and Low Coordination in Phosphorus Chemistry (Eds.: M. Regitz, O. J. Scherer), Thieme, Stuttgart, 1990, pp. 157.
23. CRC Handbook of Chemistry and Physics, 73rd Ed. (Ed.: D. R. Lide), CRC Press, Boca Raton, 1992, p. 1124.
24. [12a] G. Becker, W. Becker, R. Knebel, H. Schmidt, M. Mildenbrand, M. Westerhausen, Phosphorus Sulfur 1987, 30, 349-352. -
25. [12b] G. Becker, W. Becker, R. Knebel, H. Schmidt, U. Weber, M. Westerhausen, Nova Acta Leopold. (Neue Folge) 1985, 59, 55-67.
26. [13a] W. Rösch, T. Allspach, U. Bergsträßer, M. Regitz in Synthetic Methods of Organometallic and Inorganic Chemistry (Ed: W. A. Herrmann), Vol. 3, Thieme, Stuttgart, 1996, pp. 11. -
27. [13b] W. Rösch, U. Hees, M. Regitz, Chem. Ber. 1987, 120, 1645-1652.
28. G. M. Sheldrick, SHELXS-86, Programm for Crystal Structure Solution, University of Göttingen, 1990.
29. G. M. Sheldrick, SHELXL-93, Program for Crystal Structure Refinement, University of Göttingen, 1993.