Hydrolysis of (η5-C5Me5)MMe4 (M = Mo, W) and the formation of organometallic oxides with μ3-CH methylidyne and μ-CH2 methylidene groups: Model compounds for catalysis on metal oxide surfaces

Organometallics

Volumn 19, Issue 8, 2000, Pages 1549-1555

  Guzyr, Olexandr I ^a   Prust, Jörg ^a   Roesky, Herbert W ^a   Lehmann, Christopher ^a   Teichert, Markus ^a   Cimpoesu, Fanica ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CRYSTAL STRUCTURE; HYDROLYSIS; REACTION KINETICS; X RAY CRYSTALLOGRAPHY;

METHYLIDENE GROUPS; ORGANOMETALLIC OXIDES;

ORGANOMETALLICS;

EID: 0033751522     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000062y     Document Type: Article

References (65)

1. (a) Rao, C. N. R.; Raveau, B. Transition Metal Oxides; VCH: Weinheim, Germany, 1995.
2. (b) Thomas, J. M.; Thomas, W. J. Principles and Practice of Heterogeneous Catalysis; VCH: Weinheim, Germany, 1997, and references therein,
3. (c) Ertl, G.; Knözinger, H.; Weitkamp, J. Handbook of Heterogeneous Catalysis; VCH: Weinheim, Germany, 1997, and references therein,
4. (d) Cornell, R. M.; Schwertmann, U. The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses, VCH: Weinheim, Germany, 1996.
5. (a) Cornils, B.; Herrmann, W. A. Applied Homogeneous Catalysis with Organometallic Compounds; VCH: Weinheim, Germany, 1996, and references therein,
6. (b) Herrmann, W. A. Angew. Chem. 1982, 94, 118;
7. Angew. Chem., Int. Ed. Engl. 1982, 21, 117.
8. (a) Ivin, K. J. Olefin Metathesis; Academic Press: London, 1983, and references therein,
9. (b) Ivin, K. J.; Mol, J. C. Olefin Metathesis and Metathesis Polymerisation; Academic Press: New York, 1997.
10. (c) Bottomley, F.; Sutin, L. Adv. Organomet. Chem. 1988, 28, 339.
11. (d) Mocella, M. T.; Rovner, R.; Muetterties, E. L. J. Am. Chem. Soc. 1976, 98,4689.
12. (e) Muetterties, E. L.; Band, E. J. Am. Chem. Soc. 1980, 102, 6572.
13. (f) Kress, J. R. M.; Russell, M. J. M.; Wesolek, M. G.; Osborn, J. A. J. Chem. Soc., Chem. Commun. 1980, 431.
14. (a) Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1 and references therein,
15. (b) Schrock, R. R. Acc. Chem. Res. 1990, 23, 158 and references therein,
16. (b) Schrock, R. R.; Luo, S.; Lee, J. C., Jr.; Zanetti, N. C.; Davis, W. M. J. Am. Chem. Soc. 1996, 118, 3883.
17. (c) Weinstock, I. A.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1991, 113, 135.
18. (d) Kress, J.; Wesolek, M.; Osborn, J. A. J. Chem. Soc., Chem. Commun. 1982, 514.
19. (a) Herrmann, W. A.; Stumpf, A. W.; Priermeier, T.; Bogdanovic, S.; Dufaud, V.; Basset, J.-M. Angew. Chem. 1996, 103, 2978;
20. Angew. Chem., Int. Ed. Engl. 1996, 35, 2803.
21. (b) Dufaud, V.; Niccolai, G. P.; Thivolle-Cazat, J.; Basset, J.-M. J. Am. Chem. Soc. 1995, 117, 4288.
22. (c) Vidal, V.; Théolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595.
23. (d) Vidal, V.; Théolier, A.; Thivolle-Cazat, J.; Basset, J.-M. Science 1997, 276, 99.
24. (a) Herrmann, W. A.; Reiter, B.; Biersack, H. J. Organomet. Chem. 1975, 97, 245.
25. (b) Creswick, M.; Bernal, I.; Herrmann, W. A. J. Organomet. Chem. 1979, 172, C39.
26. (a) Herrmann, W. A. Pure Appl. Chem. 1982, 54, 65.
27. (b) Herrmann, W. A. J. Organomet. Chem. 1983, 250, 319.
28. (c) Holton, J.; Lappert, M. F.; Pearce, R.; Yarrow, P. I. W. Chem. Rev. 1983, 83, 135.
29. (d) Maitlis, P. M. J. Organomet. Chem. 1995, 500, 239.
30. (e) Maitlis, P. M.; Long, H. C.; Quyoum, R.; Turner, M. L.; Wang, Z.-Q. Chem. Commun. 1996, 1.
31. (a) Chisholm, M. H.; Hoffman, D. M.; Huffman, J. C. Inorg. Chem. 1984, 23, 3683.
32. (b) Chisholm, M. H.; Foiling, K.; Heppert, J. A.; Hoffman, D. M.; Huffman, J. C. J. Am. Chem. Soc. 1985, 107, 1234.
33. (c) Chisholm, M. H.; Conroy, B. K.; Eichhorn, B. W.; Foiling, K.; Huffman, D. M.; Huffman, J. C.; Marchant, N. S. Polyhedron 1987, 6, 783.
34. (a) Chisholm, M. H.; Lucas, E. A.; Sousa, A. C.; Huffman, J. C.; Folting, K.; Lobkovsky, E. B.; Streib, W. E. J. Chem. Soc., Chem. Commun. 1991, 847.
35. (b) Chisholm, M. H.; Huffman, J. C.; Lucas, E. A.; Sousa, A.; Streib, W. E. J. Am. Chem. Soc. 1992, 114, 2710.
36. Gouzyr, A. I.; Wessel, H.; Barnes, C. E.; Roesky, H. W.; Teichert, M.; Usón, I. Inorg. Chem. 1997, 36, 3392.
37. (a) Fischer, H.; Zeuner, S.; Ackermann, K. J. Chem. Soc., Chem. Commun. 1984, 684.
38. (b) Fischer, H.; Zeuner, S.; Ackermann, K.; Schmid, J. Chem. Ber. 1986, 119, 1546.
39. Liu, A. H.; Murray, R. C.; Dewan, J. C.; Santarsiero, B. D.; Schrock, R. R. J. Am. Chem. Soc. 1987, 109, 4282.
40. Chisholm, M. H.; Folting, K.; Huffman, J. C.; Klang, J. A.; Streib, W. E. Organometallics 1989, 8, 89.
41. Churchill, M. R.; Youngs, W. J. Inorg. Chem. 1979, 18, 2454.
42. Legzdins, P.; Rettig, S. J.; Sánchez, L. Organometallics 1985, 4, 1470.
43. (a) Faller, J. W.; Ma, Y. J. Organomet. Chem. 1989, 368, 45.
44. (b) Faller, J. W.; Ma, Y. Organometallics 1988, 7, 559.
45. Noh, S.-K.; Heintz, R. A.; Haggerty, B. S.; Rheingold, A. L.; Theopold, K H. J. Am. Chem. Soc. 1992, 114, 1892.
46. Preut, H.; Varbelow, H.-G.; Naumann, D. Acta Crystallogr. 1990, C46, 2460.
47. Chisholm, M. H.; Hoffman, D. M.; Huffman, J. C. Inorg. Chem. 1983, 22, 2903.
48. (a) Feinstein-Jaffe, I.; Pedersen, S. F.; Schrock, R. R. J. Am. Chem. Soc. 1983, 705, 7176.
49. (b) Feinstein-Jaffe, I.; Gibson, D.; Lippard, S. J.; Schrock, R. R.; Spool, A. J. Am. Chem. Soc. 1984, 106, 6305.
50. Noh, S. K.; Heintz, R. A.; Janiak, C.; Sendlinger, S. C.; Theopold, K. H. Angew. Chem. 1990, 102, 805;
51. Angew. Chem., Int. Ed. Engl. 1990, 29, 775.
52. de Jesús, E.; de Miguel, A. V.; Royo, P.; Lanfredi, A. M. M.; Tiripicchio, A. J. Chem Soc., Dalton Trans. 1990, 2779.
53. The calculations were carried out with the GAMESS package at the ab initio level; see: Schmidt, M. W.; Baldridge, K. K.; Boatz, J. A.; Elbert, S. T.; Gordon, M. S.; Jensen, J. H.; Koseki, S.; Matsunaga, N.; Nguyen, K. A.; Su, S.; Windus, T. L.; Dupuis, M.; Montgomery, J. A., Jr. J. Comput. Chem. 1993, 14, 1347. For the molybdenum complexes the STO-3G basis was used, while the tungsten complexes were treated within the MINI basis. Given the experimentally detected diamagnetism of the compounds, they were determined in the RHF limit.
54. Bader, R. F. W. Atoms in Molecules: A Quantum Theory; Clarendon Press: Oxford, U.K., 1990.
55. (a) Bottomley, F. Polyhedron 1992, 11, 1707 and references therein,
56. (b) Jiang, Y.; Tang, A.; Hoffmann, R.; Huang, J.; Lu, J. Organometallics 1985,4, 27.
57. (c) Shaik, S.; Hoffmann, R.; Fisel, C. R.; Summerville, R. H. J. Am. Chem. Soc. 1980, 102, 4555.
58. (d) Tremel, W.; Hoffmann, R.; Jemmis, E. D. Inorg. Chem. 1989, 28, 1213.
59. (e) Pinhas, A. R.; Hoffmann, R. Inorg. Chem. 1979, 18, 654.
60. (f) Teo, B. K.; Hall, M. B.; Fenske, R. F.; Dahl, L. F. Inorg. Chem. 1975, 14, 3103.
61. Guzyr, O. I.; Roesky, H. W. Unpublished results.
62. Schrock, R. R.; Kolodziej, R. M.; Liu, A. H.; Davis, W. M.; Vale, M. G. J. Am. Chem. Soc. 1990, 112, 4338.
63. Murugavel, R.; Chandrasekhar, V.; Voigt, A.; Roesky, H. W.; Schmidt, H.-G.; Noltemeyer, M. Organometallics 1995, 14, 5298.
64. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467.
65. Sheldrick, G. M. SHELXL: Program for Crystal Structure Refinement; University of Göttingen, Göttingen, Germany, 1997.