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A similar effect has been observed for related aryl substituents in polysilanes: Miller, R. D., personal communication.
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Yields were estimated from the GPC trace of the reaction mixture
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Yields were estimated from the GPC trace of the reaction mixture.
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2 monomer units via the following equation: degree of polymerization = (molecular weight based on polystyrene standards/104) × 2 × (covalent radius of carbon/covalent radius of tin). We thank Prof. John Harrod for suggesting this approximation.
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