Al-, Nb-, and Ta-based perfluoroaryloxide anions as cocatalysts for metallocene-mediated Ziegler-Natta olefin polymerization

Organometallics

Volumn 19, Issue 9, 2000, Pages 1625-1627

  Sun, Yimin ^a   Metz, Matthew V ^a   Stern, Charlotte L ^a   Marks, Tobin J ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM COMPOUNDS; FLUORINE COMPOUNDS; NEGATIVE IONS; NIOBIUM COMPOUNDS; OLEFINS; POLYMERIZATION; POSITIVE IONS; TANTALUM COMPOUNDS;

PERFLUOROARYLOXIDE;

ORGANOMETALLICS;

EID: 0033742721     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990946l     Document Type: Article

References (42)

1. (a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428-447.
2. (b) Marks, T. J., Stevens, J. C., Eds. Topics Catal. 1999, 15 (special issue).
3. Jordan, R. F., Ed. J. Mol. Catal. 1998, 128 (special issue).
4. (d) Kaminsky, W.; Arndt, M. Adv. Polym. Sci. 1997, 127, 144-187.
5. (e) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255-270.
6. (f) Brintzinger, H.-H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143-1170.
7. (g) Soga, K.; Terano, M. In Catalyst Design for Tailor-Made Polyolefins; Soga, K., Terano, M., Eds.; Elsevier: Tokyo, 1994.
8. (h) Möhring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1-29.
9. (a) Coevoet, D.; Cramail, H.; Deffieux, A. Macromol. Chem. Phys. 1998, 199, 1459-1464, and references therein.
10. (b) Reddy, S. S.; Sivaram, S. Prag. Polym. Sci. 1995, 20, 309-367.
11. (c) Harlan, C. J.; Bott, S. G.; Barron, A. R. J. Am. Chem. Soc. 1995, 117, 6465-6474.
12. (d) Sishta, C.; Hathorn, R.; Marks, T. J. J. Am. Chem. Soc. 1992, 114, 1112-4.
13. (e) Pasynkiewicz, S. Polyhedron 1990, 9, 429-453.
14. (a) Luo, L.; Marks, T. J. In ref 1b, pp 97-106.
15. (b) Li, L.; Marks, T. J. Organometallics 1998, 17, 3996-4003.
16. (c) Deck, P. A.; Beswick, C. L.; Marks, T. J. J. Am. Chem. Soc. 1998, 120, 1772-1784.
17. (d) Piers, W. E.; Chivers, T. Chem. Soc. Rev. 1997, 26, 345-354.
18. (e) Pellecchia, C.; Pappalardo, D.; Oliva, L.; Zambelli, A. J. Am. Chem. Soc. 1995, 117, 6593-6594.
19. (f) Temme, B.; Erker, G.; Karl, J.; LuRmann, H.; Fröhlich, R.; Kotila, S. Angew. Chem., Int. Ed. Engl. 1995, 34, 1755-1757.
20. (g) Yang, X. M.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015-10031.
21. (h) Bochmann, M.; Lancaster, S. J.; Hursthous, M. B.; Malik, K. M. A. Organometallics 1994, 13, 2235-2243.
22. (a) Chen, Y. X.; Metz, M. V.; Li, L. T.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1998, 120, 6287-6305.
23. (b) Chen, Y. X.; Stern, C. L.; Yang, S. T.; Marks, T. J. J. Am. Chem. Soc. 1996, 118, 12451-12452.
24. (a) Jia, L.; Yang, X.; Stern, C. L.; Marks, T. J. Organometallics 1997, 16, 842-857.
25. (b) Chien, J. C. W.; Tsai, W.-M.; Rausch, M. D. J. Am. Chem. Soc. 1991, 113, 8570-8571.
26. (c) Yang, X. M.; Stern, C. L.; Marks, T. J. Organometallics 1991, 10, 840-842.
27. (d) Ewen, J. A.; Elder, M. J.; Ewen, J. A.; Elder, M. J. European Patent Appl. p 426637, 1991.
28. (e) Hlatky, G. G.; Upton, D. J.; Turner, H. W. U.S. Patent Appl. p 459921, 1990.
29. (a) Lanza, G.; Fragalà, I. L.; Marks, T. J. J. Am. Chem. Soc. 1998, 120, 8257-8258.
30. (b) Rhodes, B.; Chien, J. C. W.; Rausch, M. D. Organometallics 1998, 17, 1931-1933.
31. (c) Shiomura, T.; Asanuma, T.; Inoue, N. Macromol. Rapid Commun. 1996, 17, 9-14.
32. Eisch, J. J.; Pombrik, S. I.; Gurtzgen, S.; Rieger, R.; Vzick, W. In ref 1g, pp 221-235.
33. (e) Giardello, M. A.; Eisen, M. S.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1995, 117, 12114-12129.
34. Communicated in part: Sun, Y.; Stern, C. L.; Marks, T. J. Abstracts of Papers; 217th National Meeting of the American Chemical Society, Anaheim, CA, April, 1999; American Chemical Society: Washington, DC, 1999; INOR 14.
35. - has been reported: Barbarich, T. J.; Handy, S. T.; Miller, S. M.; Anderson, O. P.; Grieco, P. A.; Strauss, S. H. Inorg. Chim. Acta. 1996, 3776.
36. See Supporting Information for full synthetic and characterization details.
37. - has been reported: Rockwell, J. J.; Kloster, G. M.; DuBay, W. J.; Grieco, P. A.; Shriver, D. F.; Strauss, S. H. Inorg. Chim. Acta 1997, 195-200.
38. Amor, J. I.; Burton, N. C.; Cuenca, T.; Gómez-Sal, P.; Royo, P. J. Organomet. Chem. 1995, 485, 153-160.
39. +⋯F-C examples, see: (a) Sun, Y.; Spence, R. E.v. H.; Piers, W. E.; Parvez, M.; Yap, G. P. A. J. Am. Chem. Soc. 1997, 119, 5132-5143.
40. (b) Ruwwe, J.; Erker, G.; Fröhlich, R. Angew. Chem., Int. Ed. Engl. 1996, 35, 80-83.
41. (c) Horton, A. D.; Orpen, A. G. Organometallics 1991, 10, 3910-3918.
42. F-F = 22.9 Hz).