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Volumn 19, Issue 8, 2000, Pages 1470-1476

Mechanistic studies of alkene/CO polymerization with palladium complexes promoted by B(C6F5)3

Author keywords

[No Author keywords available]

Indexed keywords

BORON COMPOUNDS; CARBON MONOXIDE; CATALYSTS; FLUORINE COMPOUNDS; MONOMERS; ORGANOMETALLICS; PALLADIUM COMPOUNDS; POLYMERIZATION; POLYOLEFINS;

EID: 0033742607     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990911l     Document Type: Article
Times cited : (37)

References (46)
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  • 3
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    • and references therein
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    • Gray, A.1
  • 4
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    • Eur. Pat. Appl. 121,965, 1984
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    • Eur. Pat. Appl. 619335
    • 3 see: Cooley, N. A.; Kirk, A. P. Eur. Pat. Appl. 619335; Chem. Abstr. 1995, 112, 550920.
    • (1995) Chem. Abstr. , vol.112 , pp. 550920
    • Cooley, N.A.1    Kirk, A.P.2
  • 18
    • 33646278939 scopus 로고    scopus 로고
    • note
    • Based on the assumption that Mn as determined by gel permeation chromatography of a polymer solution in hexafluoro-2-propanol relative to a poly(methyl methacrylate) standard is approximately 3 times the absolute value.
  • 28
    • 33845554220 scopus 로고
    • For selected reviews and monographs, see: (c) Suzuki, A. Ace. Chem. Res. 1982, 15, 178.
    • (1982) Ace. Chem. Res. , vol.15 , pp. 178
    • Suzuki, A.1
  • 34
    • 33646285580 scopus 로고    scopus 로고
    • Diedrich, F., Stang, P. J., Eds.; Wiley-VCH: Weinheim, Germany, Chapter 2
    • Suzuki, A. In Metal-Catalysed Cross Coupling Reactions; Diedrich, F., Stang, P. J., Eds.; Wiley-VCH: Weinheim, Germany, 1998; Chapter 2.
    • (1998) Metal-Catalysed Cross Coupling Reactions
    • Suzuki, A.1
  • 35
    • 33646297726 scopus 로고    scopus 로고
    • note
    • Electron-withdrawing substutents on the aryl groups of the borane would be expected to slow the rate of aryl transfer for a reaction pathway analogous to, for example, the proton-induced cleavage of aryl borates (see ref 15). The opposite substituent dependency is observed in the present case.
  • 39
    • 33646312337 scopus 로고    scopus 로고
    • note
    • 3 under standard conditions (see Experimental Section) were found to be identical, within experimental error.
  • 40
    • 33646329004 scopus 로고    scopus 로고
    • See ref 3 for example
    • See ref 3 for example.
  • 41
    • 33646335210 scopus 로고    scopus 로고
    • note
    • 3 and higher concentrations of both catalyst components were employed.
  • 42
    • 33646289995 scopus 로고    scopus 로고
    • 1b
    • 1b
  • 46
    • 33646292387 scopus 로고    scopus 로고
    • P-F coupling was highly complex in this case, and JPF coupling constants could not be determined
    • P-F coupling was highly complex in this case, and JPF coupling constants could not be determined.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.