Absolute CH radical concentrations in rich low-pressure methane-oxygen-argon flames via cavity ringdown spectroscopy of the A2Δ-X2Π transition

Journal of Physical Chemistry A

Volumn 104, Issue 21, 2000, Pages 4953-4961

  Thoman Jr , John W ^a   McIlroy, Andrew ^b  

^a WILLIAMS COLLEGE   (United States)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARGON; FUEL BURNERS; HYDROCARBONS; MATHEMATICAL MODELS; NUMERICAL ANALYSIS; OXYGEN; PHASE TRANSITIONS; PRESSURE EFFECTS; SIGNAL TO NOISE RATIO; SPECTROSCOPY; STOICHIOMETRY;

CAVITY RINGDOWN SPECTROSCOPY; FLAT FLAME BURNER; METHYLIDYNE RADICAL CONCENTRATIONS;

FREE RADICAL REACTIONS;

EID: 0033740511     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0001687     Document Type: Article

References (54)

1. Miller, J. A.; Bowman, C. T. Prog. Energy Combust. Sei. 1989, 15, 287-338.
2. Raiche, G. A.; Jeffries, J. B. Appl. Opt. 1993, 28, 4629-4635.
3. Najm, H. N.; Paul, P. H.; Mueller, C. J.; Wyckoff, P. S. Combust. Flame 1998, 113, 312-332.
4. Smith, G. P.; Golden, D. M.; Frenklach, M.; Moriarty, N. W.; Eiteneer, B.; Goldenberg, M.; Bowman, C. T.; Hanson, R.; Song, S.; W. C. Gardiner, J.; Lissianski, V.; Qin, Z. Methane Combustion Kinetics Mechanism, Version 3.0; sponsored by the Gas Research Institute, available at http:/www.me.berkeley.edu/gri-mech/:.
5. Najm, H. N.; Knio, O. M.; Paul, P. H.; Wyckoff, P. S. Comb. Sei. Technol. 1998, 140, 369.
6. Paul, P. H.; Dec, J. E. Opt. Lett. 1994, 19, 998-1000.
7. Bernath, P. F.; Brazier, C. R.; OIsen, T.; Hailey, R.; Fernando, W. T. M.; Woods, C.; Hardwick, J. L. J. Mol. Spectrosc. 1991, 147, 16-26.
8. Luque, J.; Crosley, D. R. Appl. Phys. B 1996, 63, 91-98.
9. Salmon, J. T.; Laurendeau, N. M. Appl. Opt. 1985, 24, 65-73.
10. Renfro, M. W.; Klassen, M. S.; King, G. B.; Laurendeau, N. M. Opt. Lett. 1997, 22, 175-177.
11. Williams, S.; Green, D. S.; Sethuraman, S.; Zare, R. N. J. Am. Client. Soc. 1992, 114, 9122.
12. Green, D. S.; Owano, T. C.; Williams, S.; Goodwin, D. G.; Zare, R. N.; Kruger, C. H. Science 1993, 259,.1726-1729.
13. Kumar, A.; Hsiao, C. C.; Hung, W. C.; Lee, Y. P. J. Client. Phys. 1998, 709, 3824-3830.
14. Li, X.; Kumar, A.; Hsiao, C.-C.; Lee, Y.-P. J. Phys. Client. 1999, 103, 6162-6166.
15. Li, X.; Lee, Y.-P. J. Client. Phys. 1999, 111, 4942-4947.
16. Peterson, K. A.; Oh, D. B. Opt. Lett. 1999, 24, 667-669.
17. Doerk, T.; Hertl, M.; Pfelzer, B.; Hadrich, S.; Jauernik, P.; Uhlenbusch, J. Appl. Phys. B 1997, 64, 111.
18. O'Keefe, A.; Deacon, D. A. G. Rev. Sei. Instrum. 1988, 59, 25442551.
19. Scherer, J. J.; Paul, J. B.; O'Keefe, A.; Saykally, R. J. Chem. Rev. 1998, 97, 25-51.
20. Cavity Ringdouri Spectroscopy: An Ultratrace-Absorption Measurement Technique; Busch, K. W., Busch, M. A., Eds.; American Chemical Society: Washington, DC, 1999; Vol. 720.
21. Meijer, G.; Boogaarts, M. G. H.; Jonama, R. T.; Parker, D. H.; Wodtke, A. M. Chem. Phys. Lett. 1994, 217, U2-116.
22. Lozovsky, V. A.; Derzy, L; Cheskis, S. Chem. Phys. Lett. 1998, 284, 407-411.
23. McIIroy, A. Chem. Phys. Lett. 1998, 296, 151-158.
24. Scherer, J. J.; Aniolek, K. W.; Cernansky, N. P.; Rakestraw, D. J. J. Cliem. Phys. 1997, 707, 6196-6203
25. Scherer, J. J.; Rakestraw, D. J. Chem Phys. Lett. 1997,265, 169-176.
26. Thoman, J. W., Jr.; Tran, T.; Springfield, J.; Holdsworth, J.; Fernee, M.; Knight, A. E. W., private communication.
27. Derzy, L; Lozovsky, V. A.; Cheskis, S. Chem Phys. Lett. 1999, 306, 319-324.
28. Mercier, X.; Jamette, P.; Pauwels, J. F.; Dessroux, P. Cite m. Phys. Lett. 1999, 305, 334-342.
29. VanderWal, R. L.;Ticich,T. M.Appl. Opt. 1999,38, 1444-1451.
30. Smith, G. P.; Frenklach, M.; Wang, H.; Bowman, C. T.; Golden, D.; Gardiner, W.; Lissianski, V.; Serauskas, R. Methane Combustion Kinetics Mechanism, Version 2.11; sponsored by the Gas Research Institute, available at http://www.me.berkeley.edu/gri-mech/:.
31. Woiki, D.; Votsmeier, M.; Davidson, D. F.; Hanson, R. K.; Bowman, C. T. Combust. Flame 1998, 113, 624-626.
32. Rohrie, M.; Petersen, E. L.; Davidson, D. F.; Hanson, R. K.; Bowman, C. f. Int. J. Chem. Kinet. 1997, 29, 781-789.
33. Markus, M. W.; Roth, P.; Just, T. Int. J. Chem. Kinet. 1996, 28, 171-179.
34. Mcllroy, A. Isr. J. Chem. 1999, 39, 55-62.
35. Luque, J.; Crosley, D. R. J. Chem. Phys. 1996, 104, 3907-3913.
36. Luque, J.; Crosley, D. R. LIFBASE: Database and 'Spectral Simulation Program (Version 1.5); SRI International, MP 99-009, 1999.
37. Beenakker, C. I. M.; Verbeek, P. J. F.; Mohlmann, G. R.; Heer, F. J. d. J. Quant. Spectrosc. Radiat. Transfer 1975, 15, 333.
38. Baas, R. Ch.; Beenakker, C. I. M. Comput. Phys. Commun. 197-4, 8, 236-245.
39. Garland, N. L.; Crosley, D. R. J. Quant. Spectrosc. Radiat. Transfer 1985, 33, 591-595.
40. Kee, R. J.; Dixon-Lewis, G.; Warnatz, J.; Coltrin, M. E.; Miller, J. A. "A Fortran Computer Code Package for the Evaluation of Gas-Phase Multicomponent Transport Properties", Sandia National Laboratories, SAND86-8246.UC-32, 1986.
41. Kee, R. J.; Grcar, J. F.; Smooke, M. D.; Miller, J. A. "A Fortran program for modeling steady laminar one-dimensional flames", Sandia National Laboratories, SAND85-8240.UC-4, 1987.
42. Kee, R. J.; Rupley, F. M.; Miller, J. A. "Chemkin II: A Fortran Chemical Kinetics Package for the Analysis of Gas-Phase Chemical Kinetics", Sandia National Laboratories, SANDS9-8009.UC-401, 1991.
43. Kee, R. J.; Rupley, F. M.; Miller, J. A. 'The Chemkin Thermodynamic Database", Sandia National Laboratories, SAND87-8251B.UC-4, 1991.
44. Prada, L.; Miller, J. A. Combust. Sei. Technol. 1998, 132, 225-250.
45. Gero, L. Z. Phys. 1941, 118, 27.
46. Zachwieja, M. J. Mol. Spectrosc. 1997, 182, 18.
47. CRC Handbook of Chemistry and Physics; 56th ed.; Weast, R. C., Ed.; CRC Press: Cleveland, OH, 1976.
48. Sappey, A. D.; Hill, E. S.; Settersten, T.; Linne, M. A. Opt. Lett. 1998, 23, 954-956.
49. Zalicki, P.; Zare, R. N. J. Chem. Phys. 1995, 102, 2708-2717.
50. Romanini, D.; Lehmann, K. K. J. Chem. Phys. 1993, 99, 6287-6301.
51. Hodges, J. T.; Looney, J. P.; Van Zee, R. D. Appl. Opt. 1996, 35, 4112-4116.
52. Taatjes, C. A. /. Phys. Chem. 1996, 100, 17840-1784.
53. Pibel, C. D.; Mcllroy, A.; Taatjes, C. A.; Alfred, S.; Patrick, K.; Halpern, J. B. J. Chem. Phys. 1999, 110, 1841-1843.
54. 2"; Nineteenth Symposium (International) on Combustion, Pittsburgh, PA, 1982.