메뉴 건너뛰기




Volumn 33, Issue 7, 2000, Pages 2397-2402

Preparation and polymerization of benzaldehyde formaldehyde azine (1-phenyl-2, 3-diaza-1, 3-butadiene)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; CHEMICAL BONDS; COMPOSITION EFFECTS; FLUORINE COMPOUNDS; INITIATORS (CHEMICAL); LITHIUM COMPOUNDS; MAGNESIUM COMPOUNDS; MOLECULAR STRUCTURE; MONOMERS; PERMITTIVITY; POLYMERIZATION; SOLVENTS;

EID: 0033734318     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma991529n     Document Type: Article
Times cited : (14)

References (29)
  • 20
    • 85037486267 scopus 로고    scopus 로고
    • Benzaldehyde hydrazone was prepared by reaction of benzaldehyde and hydrazine monohydrate in ethanol and purified by successive distillations under reduced pressure over calcium hydride: yield 88%; bp 107-110 °C (0.5 mmHg). IR (neat): 3331 (N-H), 1597 cm-1 (C=N). 'H NMR (270 MHz, CDC13): 6 5.62 (s, 2H, NH2), 7.37 (m, 3H, para and meta), 7.58 (dd, 2H, J = 8.9, 1, 7 Hz, ortho), 7.69 (s, 1H, CH=N). 13C NMR (67.9 MHz, CDC13): δ 125.6 (meta), 127.9 (ortho), 128.1 (para), 134.8 (ipso), 150.0 (C=N).
    • Benzaldehyde hydrazone was prepared by reaction of benzaldehyde and hydrazine monohydrate in ethanol and purified by successive distillations under reduced pressure over calcium hydride: yield 88%; bp 107-110 °C (0.5 mmHg). IR (neat): 3331 (N-H), 1597 cm-1 (C=N). 'H NMR (270 MHz, CDC13): 6 5.62 (s, 2H, NH2), 7.37 (m, 3H, para and meta), 7.58 (dd, 2H, J = 8.9, 1, 7 Hz, ortho), 7.69 (s, 1H, CH=N). 13C NMR (67.9 MHz, CDC13): δ 125.6 (meta), 127.9 (ortho), 128.1 (para), 134.8 (ipso), 150.0 (C=N).
  • 23
    • 12944308918 scopus 로고
    • Brame, E. G., Jr., Grasselli, J. G., Marcel Dekker: New York, Part B, Chapter 6, pp
    • Nyquist, R. A.; Kagel, R. O. In Infrared and Roman Spectroscopy; Brame, E. G., Jr., Grasselli, J. G., Eds.; Marcel Dekker: New York, 1977; Vol. I, Part B, Chapter 6, pp 480-481.
    • (1977) Infrared and Roman Spectroscopy , vol.1 , pp. 480-481
    • Nyquist, R.A.1    In, K.R.O.2
  • 26
    • 85037467401 scopus 로고    scopus 로고
    • Pale yellow crystalline product: IR(KBr): 1650 (C=N), 1600 (aromatic C=C), 1500 (aromatic C=C), 1160 (C-N), 755 (aromatic C-H), 690 cm-1 (aromatic C-H). 1H NMR (270 MHz, CDCls): ô7.46 (m, 3H, ortho and para), 7.87 (dd, 2H, J = 8.0, 3.0 Hz, meta), 8.68 (s, 1H, methine). Colorless powder: IR (KBr): 1646 (C=N), 1586 (N=N), 1500 (aromatic C=C), 1194 cm-1 (C-N).
    • Pale yellow crystalline product: IR(KBr): 1650 (C=N), 1600 (aromatic C=C), 1500 (aromatic C=C), 1160 (C-N), 755 (aromatic C-H), 690 cm-1 (aromatic C-H). 1H NMR (270 MHz, CDCls): ô7.46 (m, 3H, ortho and para), 7.87 (dd, 2H, J = 8.0, 3.0 Hz, meta), 8.68 (s, 1H, methine). Colorless powder: IR (KBr): 1646 (C=N), 1586 (N=N), 1500 (aromatic C=C), 1194 cm-1 (C-N).
  • 27
    • 33745568091 scopus 로고    scopus 로고
    • Dean, J. A., Ed.; McGraw-Hill: New York, Section 5, pp
    • Lange's Handbook of Chemistry, 15th éd.; Dean, J. A., Ed.; McGraw-Hill: New York, 1999; Section 5, pp 5.105-5.129.
    • (1999) Lange's Handbook of Chemistry, 15th Éd. , pp. 5105-5129
  • 28
    • 85037478854 scopus 로고    scopus 로고
    • +] Calcd 396. Found 396.
    • +] Calcd 396. Found 396.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.