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Volumn 104, Issue 27, 2000, Pages 6439-6446

Mechanism and stereochemistry of the water-exchange reaction on aqua pentaammine and aqua pentakis-methylamine rhodium(III) ions

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; AMMONIA; COMPUTATIONAL METHODS; DISSOCIATION; ELECTRON TRANSITIONS; ELECTRONIC STRUCTURE; ION EXCHANGE; MATHEMATICAL MODELS; POTENTIAL ENERGY; REACTION KINETICS; STEREOCHEMISTRY;

EID: 0033718270     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp000560k     Document Type: Article
Times cited : (14)

References (33)
  • 6
    • 84962459891 scopus 로고    scopus 로고
    • Submitted for publication
    • Rotzinger, F. P. Submitted for publication.
    • Rotzinger, F.P.1
  • 10
    • 84962424066 scopus 로고    scopus 로고
    • d.T: nonbonding orbitals, for example the tig levels in Oh symmetry; da: antibonding Orbitals, eglevels in Oh
    • d.T: nonbonding orbitals, for example the tig levels in Oh symmetry; da: antibonding Orbitals, eglevels in Oh.
  • 24
  • 25
    • 84962453169 scopus 로고    scopus 로고
    • note
    • 2+ and Co(NH3)jCl2+ via interchange mechanisms, similar differences in the M-C1 and M-O bond lengths have been observed.8 Also in this case, the aβ levels are populated with one or two electrons in the respective Cr1 and Co1 species.
  • 26
    • 84962402189 scopus 로고    scopus 로고
    • note
    • III and RhmO bonds are weaker, these changes might be somewhat larger and disparate for Rum and Rhm. The difference of the Rum-O and Rhm-O bond lengths is, however, expected to alter only slightly.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.