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Volumn 11, Issue 1, 2000, Pages 81-85

Reductive coupling of carbonyl compounds using lanthanum metal

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAS CHROMATOGRAPHY; IODINE; LANTHANUM; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REDUCTION; SYNTHESIS (CHEMICAL);

EID: 0033709204     PISSN: 10427163     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1098-1071(2000)11:1<81::AID-HC12>3.0.CO;2-1     Document Type: Article
Times cited : (14)

References (33)
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    • note
    • We can purchase lanthanoid metals (50 mesh) (La: ¥25,900/25 g, Ce: ¥13,000/10 g, Sm: ¥2,600/1 g, Yb: ¥13,600/5g) from Aldrich Chemical Co.
  • 18
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    • note
    • Ding and Wu have disclosed that the reaction of benzaldehyde with lanthanum metal in the presence of excess amounts of trimethylchlorosilane and i-PrOH in THF solvent proceeded efficiently to give hydrobenzoin in 91% yield. However, only one example was shown in the manuscript. See Ref. [7].
  • 19
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    • note
    • Fukuzawa has reported that lanthanum metal assisted the reaction of α-halo esters with carbonyl compounds to give the corresponding lactones in moderate to good yields along with a small amount of pinacol as a by-product. See Ref. [2b].
  • 20
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    • note
    • 3SiBr [23].


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