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Volumn 19, Issue 12, 2000, Pages 2237-2239

Observation of linkage isomerization in W(CO)5(2,5-dihydrofuran)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; CHEMICAL BONDS; INFRARED SPECTROSCOPY; ISOMERIZATION; ISOMERS; MOLECULAR STRUCTURE; PHOTOLYSIS; RATE CONSTANTS; SOLUTIONS;

EID: 0033700613     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000105a     Document Type: Article
Times cited : (12)

References (21)
  • 7
    • 12944333146 scopus 로고    scopus 로고
    • note
    • 2-C,C geometry. The diastereotopic methylene protons imply that the ring is bound face-on to the metal.
  • 8
    • 12944312714 scopus 로고    scopus 로고
    • note
    • 3
  • 18
    • 0037537302 scopus 로고
    • 5(CyH) with 4-acetylpyridine (Dobson, G. R.; Spradling, M. D. Inorg. Chem. 1990, 29, 880), it was observed that the kinetic product is O-bound, while the thermodynamic product is N-bound, but the kinetics of the isomerization were on a much slower time scale than was of interest to the authors of that study.
    • (1990) Inorg. Chem. , vol.29 , pp. 880
    • Dobson, G.R.1    Spradling, M.D.2
  • 19
    • 12944252994 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum of 1C also indicates that any exchange or isomerization that would make the methylene H atoms equivalent must be slow at room temperature.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.