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note
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2-C,C geometry. The diastereotopic methylene protons imply that the ring is bound face-on to the metal.
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8
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12944312714
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5(CyH) with 4-acetylpyridine (Dobson, G. R.; Spradling, M. D. Inorg. Chem. 1990, 29, 880), it was observed that the kinetic product is O-bound, while the thermodynamic product is N-bound, but the kinetics of the isomerization were on a much slower time scale than was of interest to the authors of that study.
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12944252994
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1H NMR spectrum of 1C also indicates that any exchange or isomerization that would make the methylene H atoms equivalent must be slow at room temperature.
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1-S, in keeping with the hard/soft acid concepts discussed here: Choi, M.-G.; Daniels, L. M.; Angelici, R. J. Inorg. Chem. 1991, 30, 3647.
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