Thermodynamic consistency of reaction mechanisms and null cycles

Journal of Chemical Physics

Volumn 112, Issue 24, 2000, Pages 10714-10717

  Schmitz, Guy ^a  

^a UNIVERSITÉ LIBRE DE BRUXELLES   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

MATHEMATICAL MODELS; THERMODYNAMIC STABILITY;

ELEMENTARY REACTIONS; NULL CYCLES;

RATE CONSTANTS;

EID: 0033685948     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.481715     Document Type: Article

References (33)

1. J. H. Espenson, in Chemical Kinetics and Reaction Mechanisms, 2nd ed. (McGraw-Hill, New York, 1995), p. 127.
2. J. O. Edwards, E. F. Greene, and J. Ross, J. Chem. Educ. 45, 381 (1968).
3. B. H. Mahan, J. Chem. Educ. 52, 299 (1975).
4. O. K. Rice, Statistical Mechanics, Thermodynamics and Kinetics (Freeman, San Francisco, 1967).
5. L. Onsager, Phys. Rev. 37, 405 (1931).
6. J. H. Espenson, Ref. 1, p. 172.
7. R. M. Noyes, R. J. Field, and R. C. Thompson, J. Am. Chem. Soc. 93, 7315 (1971).
8. As the rates are functions of the concentrations, the equilibrium constants used in this paper are apparent values including the effect of the activity coefficients.
9. S. Barkin, M. Bixon, R. M. Noyes, and K. Bar-Eli, Int. J. Chem. Kinet. 9, 841 (1977).
10. P. Dagaut, J. C. Boettner, and M. Cathonnet, J. Chim. Phys. Phys.-Chim. Biol. 89, 867 (1992).
11. M. Boumezioud and C. Tondre, J. Chim. Phys. Phys.-Chim. Biol. 85, 719 (1988).
12. C. F. Bernasconi, Investigation of Rates and Mechanisms of Reactions, Techniques of Chemistry (Wiley-Interscience, New York, 1986), Vol. VI, part II; J. H. Espenson, Ref. 1, p. 256.
13. C. F. Bernasconi, Investigation of Rates and Mechanisms of Reactions, Techniques of Chemistry (Wiley-Interscience, New York, 1986), Vol. VI, part II; J. H. Espenson, Ref. 1, p. 256.
14. G. Schmitz, J. Chim. Phys. Phys.-Chim. Biol. 93, 482 (1996).
15. Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and its Metal Chelates, IUPAC (Pergamon, New York, 1979).
16. R. M. Krupka, H. Kaplan, and K. J. Laidler, Trans. Faraday Soc. 62, 2754 (1966); K. J. Laidler, in Chemical Kinetics, 3rd ed. (Harper & Row, New York, 1987), pp. 129, 285.
17. R. M. Krupka, H. Kaplan, and K. J. Laidler, Trans. Faraday Soc. 62, 2754 (1966); K. J. Laidler, in Chemical Kinetics, 3rd ed. (Harper & Row, New York, 1987), pp. 129, 285.
18. J. H. Espenson, in Chemical Kinetics and Reaction Mechanisms, 2nd ed. (McGraw-Hill, New York, 1995), p. 127.
19. J. O. Edwards, E. F. Greene, and J. Ross, J. Chem. Educ. 45, 381 (1968).
20. B. H. Mahan, J. Chem. Educ. 52, 299 (1975).
21. O. K. Rice, Statistical Mechanics, Thermodynamics and Kinetics (Freeman, San Francisco, 1967).
22. L. Onsager, Phys. Rev. 37, 405 (1931).
23. J. H. Espenson, Ref. 1, p. 172.
24. R. M. Noyes, R. J. Field, and R. C. Thompson, J. Am. Chem. Soc. 93, 7315 (1971).
25. As the rates are functions of the concentrations, the equilibrium constants used in this paper are apparent values including the effect of the activity coefficients.
26. S. Barkin, M. Bixon, R. M. Noyes, and K. Bar-Eli, Int. J. Chem. Kinet. 9, 841 (1977).
27. P. Dagaut, J. C. Boettner, and M. Cathonnet, J. Chim. Phys. Phys.-Chim. Biol. 89, 867 (1992).
28. M. Boumezioud and C. Tondre, J. Chim. Phys. Phys.-Chim. Biol. 85, 719 (1988).
29. C. F. Bernasconi, Investigation of Rates and Mechanisms of Reactions, Techniques of Chemistry (Wiley-Interscience, New York, 1986), Vol. VI, part II; J. H. Espenson, Ref. 1, p. 256.
30. G. Schmitz, J. Chim. Phys. Phys.-Chim. Biol. 93, 482 (1996).
31. Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and its Metal Chelates, IUPAC (Pergamon, New York, 1979).
32. R. M. Krupka, H. Kaplan, and K. J. Laidler, Trans. Faraday Soc. 62, 2754 (1966);
33. K. J. Laidler, in Chemical Kinetics, 3rd ed. (Harper & Row, New York, 1987), pp. 129, 285.