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Volumn 40, Issue 31, 1999, Pages 5735-5738

Oxidative resolution of 2-cyclopentenols by the asymmetric hydrogen transfer protocol

Author keywords

Catalysis; Enantioselection; Oxidation; Ruthenium and compounds; Transfer reactions

Indexed keywords

CYCLOPENTENE DERIVATIVE; CYCLOPENTENONE DERIVATIVE; HYDROGEN; RUTHENIUM COMPLEX;

EID: 0033618384     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01087-4     Document Type: Article
Times cited : (27)

References (20)
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    • Related papers, see: Hashiguchi, S.; Fujii A.; Takehara, J.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1995, 117, 7562. Takehara, J.; Hashiguchi, S.; Fujii A.; Inoue, S.; Ikariya, T.; Noyori, R. Chem.commun. 1996, 233. Fujii A.; Hashiguchi, S.; Uematsu, N.; Ikariya, T.; Noyori, R. J. Am. Chem.soc. 1996, 118. 2521. Uematsu, N.; Fujii A.; Hashiguchi, S.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1996, 118, 4916. Ohta, T.; Nakahara, S.; Shigemura, Y.; Hattori, K.; Furukawa, I. Chem. Lett.1998, 491. Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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    • Related papers, see: Hashiguchi, S.; Fujii A.; Takehara, J.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1995, 117, 7562. Takehara, J.; Hashiguchi, S.; Fujii A.; Inoue, S.; Ikariya, T.; Noyori, R. Chem.commun. 1996, 233. Fujii A.; Hashiguchi, S.; Uematsu, N.; Ikariya, T.; Noyori, R. J. Am. Chem.soc. 1996, 118. 2521. Uematsu, N.; Fujii A.; Hashiguchi, S.; Ikariya, T.; Noyori, R. J. Am. Chem.soc. 1996, 118, 4916. Ohta, T.; Nakahara, S.; Shigemura, Y.; Hattori, K.; Furukawa, I. Chem. Lett. 1998, 491. Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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    • We have demonstrated that the tricyclic allyl alcohol having an α-methyl functionality (±)-4 (OR=H) afforded the corresponding enone 2 (OR=H) in high enantiomeric excess under the same conditions, see: Kanada, R. M.; Taniguchi, T.; Ogasawara, K. Chem. Commun. 1998, 1755.
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