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0344766575
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note
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In general, the Soret band is difficult to measure at low temperature without severe distortion as it is invariably superimposed upon a sloping baseline due to Rayleigh scattering from the microstructure of the frozen glass. The scattering rapidly increases in the near-ultraviolet, and consequently, even at concentrations more dilute than those employed in the present study, samples are opaque (or nearly so) in the Soret region. Therefore, for most practical purposes, the reliable recording of this absorption band at cryogenic temperatures in semiaqueous glasses intended primarily for magnetooptical measurements is precluded.
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0345197046
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note
-
It might not be appropriate to simply attribute the band shape of Figure 4C to the temperature-dependent terms in eq 1, since this expression was derived to describe transitions from either singlet ground states or degenerate manifolds under nonsaturating conditions.
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32
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0010720334
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0345629060
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note
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2h point groups.
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35
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0344766572
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note
-
u parentage of the singlet states and more clearly associate these states with the coordinate axes of the molecular frame.
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36
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36849099150
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0345629059
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2 term in eq 1.
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38
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0010973077
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0345197043
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note
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-1. The shoulder observed near the maximum of the Q band in Figure 3A is due to differences in either bandwidths or amplitudes associated with the two transitions, which are close to the limit of resolution.
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41
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0345629058
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Ph.D. Thesis, University of California, Berkeley
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