Tandem use of reductive and radical cyclization protocols in an approach to the first σ-allyl cation

Tetrahedron Letters

Volumn 40, Issue 18, 1999, Pages 3499-3502

  Paquette, Leo A ^a   Usui, Shuji ^a,b  

^a OHIO STATE UNIVERSITY   (United States)

^b HIROSHIMA INTERNATIONAL UNIVERSITY   (Japan)

Author keywords

Cyclization; Polyquinanes; Reduction; Ring transformations; Sulfur compounds

Indexed keywords

CATION; IODINE; MAGNESIUM; SILANE DERIVATIVE; SULFUR DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; MOLECULAR INTERACTION; REACTION ANALYSIS; REDUCTION; TEMPERATURE DEPENDENCE;

EID: 0033617179     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00541-9     Document Type: Article

References (11)

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2. [2] Lipkowitz, K. B.; Larter, R. M.; Boyd, D. B. J. Am. Chem. Soc. 1980, 102, 85.
3. [3] For a review of three-center two-electron bonding, see McMurry, J. E.; Lectka, T. Acc. Chem. Res. 1992, 25, 47.
4. [4] Baldridge, K. K.; Leahy, J.; Siegel, J. S. following paper.
5. [5] Usui, S.; Paquette, L. A. preceding paper in this issue.
6. [6] Corey, E. J.; Pyne, S. G. Tetrahedron Lett. 1983, 24, 2821.
7. [7] Ikeda, T.; Yue, S.; Hutchinson, C. R. J. Org. Chem. 1985, 50 5193.
8. [8] Barton, D H. R.; McCombie, S. W. J. Chem. Soc., Perkin Trans. 1 1975, 1574.
9. [9] Karger, M. H.; Mazur, Y. J. Am. Chem. Soc. 1968, 90, 3878.
10. [10] Chatgilialoglu, C. Acc. Chem. Res. 1992, 25, 188.
11. 13C NMR, and MS spectral data in satisfactory agreement with the assigned structures.