Synthesis, structure, and nucleophile-induced rearrangements of spiroketones

Journal of Organic Chemistry

Volumn 64, Issue 22, 1999, Pages 8201-8209

  Maslak, Przemyslaw ^a   Varadarajan, Sridhar ^a   Burkey, Jeffrey D ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

KETONE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; MOLECULAR INTERACTION; POLYMERIZATION; SYNTHESIS;

EID: 0033615497     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo990867j     Document Type: Article

References (21)

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3. (c) Maslak, P.; Chopra, A.; Moylan, C. R.; Wortmann, R.; Lebus, S.; Rheingold, A. L.; Yap, G. P. A. J. Am. Chem. Soc. 1996, 118, 1471.
4. (d) Maslak, P.; Chopra, J. Am. Chem. Soc. 1993, 115, 9331.
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9. The semiempirical MNDO-PM3 calculations (Stewart, J. J. P. J. Comp-Aid. Mol. Des. 1990, 4, 1) were carried out using Spartan 5 (Wavefunction Inc.).
10. The synthetic strategy followed that used to prepare dione 10 and a related spirosystem: (a) Langer, E.; Lehner, H. Tetrahedron 1973, 29, 375.
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13. The details of the crystal structure and the crystal packing of 1 and 2 will be presented elsewhere: Maslak, P.; Varadarajan S.; Rheingold, A. L.; Yap, G. P. Manuscript in preparation.
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