13C and 2H kinetic isotope effects and the mechanism of bromination of 1-pentene under synthetic conditions

Organic Letters

Volumn 1, Issue 2, 1999, Pages 327-329

  Merrigan, Steven R ^a   Singleton, Daniel A ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1 PENTENE; 1-PENTENE; ALKENE; BROMINE; CARBON; CARBON TETRACHLORIDE; DEUTERIUM;

ARTICLE; CHEMISTRY; KINETICS; SOLUTION AND SOLUBILITY;

ALKENES; BROMINE; CARBON ISOTOPES; CARBON TETRACHLORIDE; DEUTERIUM; KINETICS; SOLUTIONS;

EID: 0033614866     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol990659d     Document Type: Article

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36. The calculations used the program QUIVER (Saunders: M.; Laidig, K. E.; Wolfsberg, M. J. Am. Chem. Soc. 1989, 111, 8989) with Becke3LYP frequencies scaled by 0.9614. ( Scott, A. P.; Radom, L. J. Phys. Chem. 1996, 100, 16502.)