Hemiaminals of trifluoroacetaldehyde, as trifluoromethylating agents

Tetrahedron Letters

Volumn 40, Issue 35, 1999, Pages 6411-6414

  Mispelaere, Clotilde ^a   Roques, Nicolas ^a  

^a Rhodia Europe   (France)

Author keywords

Hemiaminal; Trifluoroacetaldehyde; Trifluoromethane; Trifluoromethylation

Indexed keywords

ACETALDEHYDE; AMINE; ANION; BENZALDEHYDE; METHANOL DERIVATIVE; TRIFLUOROACETALDEHYDE; UNCLASSIFIED DRUG;

ARTICLE; GAS LIQUID CHROMATOGRAPHY; METHYLATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS;

EID: 0033609938     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01369-6     Document Type: Article

References (8)

1. (a) Wiemers, D.M.; Burton, D.J. J. Am. Chem. Soc., 1986, 108, 832 ;
2. (b) Olah, G.A.; Chambers, R.D. Prakash, G.K.S. « Synthetic Fluorine Chemistry », Wiley Ed., 1992, p 227 ;
3. (c)Yukihisha, G.; Takeshl, H. (Daicel Chemical Industry) J.P. 0413651 (1990).
4. (a) Roques, N.; Russell, J. (Rhône-Poulenc Chimie) WO 9719038 (1995) and PCT/FR97/02062 (1997) ;
5. (b) Folleas, B.; Marek, I.; Normant, J.F.; Saint-Jalmes, L. Tetrahedron Lett., 1998, 39, 2973 ;
6. (c) Roques, N.; Russell, J., Tetrahedron, 1998, 54, 13771.
7. 3).
8. Molines, H., Wakselman, C., J.Fluorine.Chem., 1980, 16, 97.