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0344391741
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note
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→hk|, hence not resolved in GIXD from these 2D powders. E.g., for the hexagonal lattice {10} means {(10),(01),(10),(01),(11),(11)}.
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31
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4243381090
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-1 is the so-called Vineyard-Yoneda, which arises from the interference between X-rays diffracted up into the Bragg rod and rays diffracted down and then reflected up by the interface, cf.: Vineyard, G. Phys. Rev. B 1982, 26, 4146.
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0344391740
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note
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90, a deviation from the nearest neighbor direction of the tilt azimuth by 10° had to be assumed.
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33
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0345254735
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note
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r = 90°.
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34
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0003459618
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xy, over which "near-perfect" crystallinity extends in the 2-D crystallites
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xy, over which "near-perfect" crystallinity extends in the 2-D crystallites.
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X-ray Diffraction
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Guinier, A.1
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0344823474
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note
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The electron density of bulk PEG is only 6% higher than the water subphase.
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38
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0344823472
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note
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We were surprised that the monolayer roughness, σ, was not significantly increased by molecular staggering. It may be that the gauche defects and disorder, as sketched in Figure 7, cause the air-monolayer interface to have a relatively smooth appearance.
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41
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