메뉴 건너뛰기




Volumn 40, Issue 26, 1999, Pages 4833-4836

Enantiomerically pure 1,2-bis(isopropylmethylphosphino)benzene and its use in highly enantioselective Rh-catalyzed asymmetric hydrogenation

Author keywords

[No Author keywords available]

Indexed keywords

1,2 BIS(ALKYLMETHYLPHOSPHINO)ETHANE; 1,2 BIS(ISOPROPYLMETHYLPHOSPHINO)BENZENE; 1,2 BIS(METHYLPHOSPHINO)BENZENE; PHOSPHINE DERIVATIVE; RHODIUM COMPLEX; UNCLASSIFIED DRUG;

EID: 0033603422     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00856-4     Document Type: Article
Times cited : (49)

References (28)
  • 15
    • 0013568515 scopus 로고    scopus 로고
    • Ager, D. J., Ed. Marcel Dekker, Inc: New York, Chapter 18 and references therein
    • Burk and co-workers have demonstrated that 1,2-bis(trans-2, 5-dialkylphospholano)benzene ligands (DuPHOS) bearing a 1,2-phenylene backbone are extremely effective in various asymmetric hydrogenations. Burk, M. J. in Handbook of Chiral Chemicals; Ager, D. J., Ed. Marcel Dekker, Inc: New York, 1999; Chapter 18 and references therein.
    • (1999) Handbook of Chiral Chemicals
    • Burk, M.J.1
  • 18
    • 0013621266 scopus 로고    scopus 로고
    • note
    • 2: C, 58.73; H, 8.45. Found: C, 58.78; H, 8.44.
  • 19
    • 0013567653 scopus 로고    scopus 로고
    • note
    • w = 0.050, GOF 1.11, Flack parameter = 0.089(10). (formula presented)
  • 20
    • 0013594196 scopus 로고    scopus 로고
    • 2 = 10.70)
    • 2 = 10.70).
  • 21
    • 0013621896 scopus 로고    scopus 로고
    • The other isomer, (R, R)-1, was also prepared in a similar manner using dibenzoyl-L-tartaric acid ((-)-DBT)
    • The other isomer, (R, R)-1, was also prepared in a similar manner using dibenzoyl-L-tartaric acid ((-)-DBT).
  • 23
    • 0013568415 scopus 로고    scopus 로고
    • note
    • w = 0.107, GOF 2.23.
  • 24
    • 0000565505 scopus 로고    scopus 로고
    • For recent reports on Rh-catalyzed asymmetric hydrogenations, see the following: (a) Qiao, S. ; Fu, G. C. J. Org. Chem. 1998, 63, 4168.
    • (1998) J. Org. Chem. , vol.63 , pp. 4168
    • Qiao, S.1    Fu, G.C.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.