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For related processes, see: (a) Bartoli, G.; Cimarelli, C.; Dalpozzo, R.; Palmieri, G. Tetrahedron 1995, 51, 8613. (b) Huang, W. S.; Yuan, C. I. J. Chem. Soc., Perkin Trans. 1 1995, 741. (c) See also ref 5b.
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37049079689
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For related processes, see: (a) Bartoli, G.; Cimarelli, C.; Dalpozzo, R.; Palmieri, G. Tetrahedron 1995, 51, 8613. (b) Huang, W. S.; Yuan, C. I. J. Chem. Soc., Perkin Trans. 1 1995, 741. (c) See also ref 5b.
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Huang, W.S.1
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0345306839
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See also ref 5b
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For related processes, see: (a) Bartoli, G.; Cimarelli, C.; Dalpozzo, R.; Palmieri, G. Tetrahedron 1995, 51, 8613. (b) Huang, W. S.; Yuan, C. I. J. Chem. Soc., Perkin Trans. 1 1995, 741. (c) See also ref 5b.
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33
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34
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0345306837
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note
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In other examples due to overlapping peaks or broads signals, this assignment was more complex.
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36
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0007765334
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(b) Armesto, D.; Bosch, P.; Gallego, M. G.; Martín, J. F.; Ortíz, M. J.; Pérez Osorio, R.; Ramos, A. Org. Prep. Proced. Int. 1987, 19, 181.
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Ortíz, M.J.5
Pérez Osorio, R.6
Ramos, A.7
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38
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0001180149
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0001093043
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Ono, T.; Kuhkar, V. P.; Soloshonok, V. A. J. Org. Chem. 1996, 61, 6563.
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43
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0000485579
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Barluenga, J.; Jardón, J.; Gotor, V. J. Org. Chem. 1985, 50, 802.
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Hojo, M.; Masuda, R.; Okada, E.; Sakaguchi, S.; Narumiya, H.; Morimoto, K. Tetrahedron Lett. 1989, 30, 6173.
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-
48
-
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0344875721
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note
-
In fact, Hojo methodology does not allow the synthesis of fluorinated cyclic β-enamino ketones such as 4a, 4d, and 4g (see Table 2, entries 1, 4-5, and 8).
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49
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85082547340
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For a similar reaction, see: Bartoli, G.; Cimarelli, C. Palmieri, G.; Rosco, M.; Dalpozzo R. Synthesis 1990, 895.
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Bartoli, G.1
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Dalpozzo, R.5
-
50
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0345306832
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note
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In some occasions, and only after prolonged heating, a complex mixture of products along with starting material was identified in the crude reaction mixture.
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-
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51
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0344012679
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note
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The synthetic utility of related nonfluorinated derivatives has been successfully studied by Barluenga's group (see refs 9, 11, and 16).
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52
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