A resolution of the monodentate P*-chiral phosphine PBU(t)C6H4Br-4 and its NMR-deduced absolute configuration

Tetrahedron Asymmetry

Volumn 10, Issue 8, 1999, Pages 1483-1497

  Dunina, Valery V ^a   Kuz'mina, Lyudmila G ^b   Rubina, Marina Yu ^a   Grishin, Yuri K ^a   Veits, Yuri A ^a   Kazakova, Elena I ^c  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

^b KURNAKOV INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Russian Federation)

^c SYKTYVKAR STATE UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

BENZYLAMINE DERIVATIVE; PALLADIUM COMPLEX; PHOSPHINE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CHROMATOGRAPHY; DIASTEREOISOMER; ENANTIOMER; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; X RAY DIFFRACTION;

EID: 0033597446     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(99)00134-2     Document Type: Article

References (111)

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57. 13. TLC testing of diastereomeric pairs 2a,b-4a,b was performed on Silufol plates using three-fold eluating with an etherheptane (1:1) mixture.
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65. 31P NMR spectra; the isomer ratio varies slightly from one sample to the other, and from one solvent to the other.
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86. 1H NM7R spectra of diastereomeric complexes:
87. 1H NM7R spectra of diastereomeric complexes:
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90. 24. The Newman projections presented on Figs. 2 and 3 were constructed with account of the real torsion angles taken from our X-ray data; the use of idealised projections (with dihedral angles 60°) may lead to erroneous conclusions.
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111. 34. The heating up to 100°C results in these signals coalescence in one broad resonance at δ 51.3 ppm.