Mixed chloride/amine complexes of dimolybdenum(II,II). 5. Experimental and theoretical study of the rotation conformational preferences of Mo2Cl4(R-py)4 (R-py = substituted pyridine) molecules

Journal of the American Chemical Society

Volumn 121, Issue 50, 1999, Pages 11758-11761

  Cotton, F Albert ^a   Dikarev, Evgeny V ^a   Gu, Jiande ^a   Herrero, Santiago ^a   Modec, Barbara ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE; CHLORIDE; MOLYBDENUM COMPLEX; PYRIDINE DERIVATIVE;

ARTICLE; CONFORMATION; CRYSTAL STRUCTURE; ENERGY; ISOMER; MOLECULAR DYNAMICS; TEMPERATURE; TRANS ISOMER;

EID: 0033596345     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992445x     Document Type: Article

References (16)

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4. Cotton, F. A.; Dikarev, E. V.; Herrero, S. Inorg. Chem. 1999, 38, 2649-2654.
5. 2) = 0.103, GOF = 1.102 for 463 parameters and 54 restraints, 6137 unique data (5619 with I > 2σ(I)), Mo-Mo 2.1467(5) Å, 〈N-Mo-Mo-N = 19.8(1)°. See Supporting Information for other structure details.
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