Cation-directed structure changes in polyoxometalate chemistry. Equilibria between isomers of bis(9-tungstophosphatodioxouranate(VI)) complexes

Journal of the American Chemical Society

Volumn 121, Issue 37, 1999, Pages 8512-8517

  Kim, Kee Chan ^a   Pope, Michael T ^a  

^a GEORGETOWN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIUM DERIVATIVE; CALCIUM DERIVATIVE; CATION; PHOSPHOTUNGSTIC ACID; POLYANION; POTASSIUM SALT; SODIUM DERIVATIVE; URANIUM DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; EQUILIBRIUM CONSTANT; ISOMER; MASS ACTION; MICHAELIS CONSTANT; PHASE TRANSITION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SYNTHESIS;

EID: 0033595459     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9909125     Document Type: Article

References (31)

1. Recent reviews include the following: Polyoxometalates. From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994; pp 1-411. Pope, M. T. In Encyclopedia of Inorganic Chemistry; King R. B., Ed.; John Wiley & Sons: Chichester, England, 1994; pp 3361-71. Okuhara, T.; Mizuno, N.; Misono, M. Adv. Catal. 1996, 41, 113. The following multiauthor special issues have also appeared: Polyoxometalates; Hill, C. L., Ed. Chem. Rev. 1998, 98, 1-387. Polyoxometalates in Catalysis; Hill, C. L., Ed. J. Mol. Catal. 1996, 114, 1-371.
2. Recent reviews include the following: Polyoxometalates. From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994; pp 1-411. Pope, M. T. In Encyclopedia of Inorganic Chemistry; King R. B., Ed.; John Wiley & Sons: Chichester, England, 1994; pp 3361-71. Okuhara, T.; Mizuno, N.; Misono, M. Adv. Catal. 1996, 41, 113. The following multiauthor special issues have also appeared: Polyoxometalates; Hill, C. L., Ed. Chem. Rev. 1998, 98, 1-387. Polyoxometalates in Catalysis; Hill, C. L., Ed. J. Mol. Catal. 1996, 114, 1-371.
3. Recent reviews include the following: Polyoxometalates. From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994; pp 1-411. Pope, M. T. In Encyclopedia of Inorganic Chemistry; King R. B., Ed.; John Wiley & Sons: Chichester, England, 1994; pp 3361-71. Okuhara, T.; Mizuno, N.; Misono, M. Adv. Catal. 1996, 41, 113. The following multiauthor special issues have also appeared: Polyoxometalates; Hill, C. L., Ed. Chem. Rev. 1998, 98, 1-387. Polyoxometalates in Catalysis; Hill, C. L., Ed. J. Mol. Catal. 1996, 114, 1-371.
4. Recent reviews include the following: Polyoxometalates. From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994; pp 1-411. Pope, M. T. In Encyclopedia of Inorganic Chemistry; King R. B., Ed.; John Wiley & Sons: Chichester, England, 1994; pp 3361-71. Okuhara, T.; Mizuno, N.; Misono, M. Adv. Catal. 1996, 41, 113. The following multiauthor special issues have also appeared: Polyoxometalates; Hill, C. L., Ed. Chem. Rev. 1998, 98, 1-387. Polyoxometalates in Catalysis; Hill, C. L., Ed. J. Mol. Catal. 1996, 114, 1-371.
5. Recent reviews include the following: Polyoxometalates. From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994; pp 1-411. Pope, M. T. In Encyclopedia of Inorganic Chemistry; King R. B., Ed.; John Wiley & Sons: Chichester, England, 1994; pp 3361-71. Okuhara, T.; Mizuno, N.; Misono, M. Adv. Catal. 1996, 41, 113. The following multiauthor special issues have also appeared: Polyoxometalates; Hill, C. L., Ed. Chem. Rev. 1998, 98, 1-387. Polyoxometalates in Catalysis; Hill, C. L., Ed. J. Mol. Catal. 1996, 114, 1-371.
6. See, for example: Myasoedov, B. F.; et al. Sov. Radiochem. (Engl. Transl.) 1990, 32, 361; 1991, 33, 550.
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11. (a) Tourné, C. M,; Tourné, G. F.; Brianso, M. C. Acta Crystallogr. 1980, B36, 2012.
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14. + in the cleft.
15. + in the cleft.
16. + in the cleft.
17. + in the cleft.
18. Domaille, P. J. Inorg. Synth. 1992, 27. 100.
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20. 2O, is believed to contain the β isomer, however (see arguments presented in Xin, F.; Pope, M. T. Organometallics 1994, 13, 4881).
21. o) out of 19 221 independent reflections. The structure of the anion is identical to that of the ammonium derivative.
22. 9 groups. Refinement demonstrated partial disorder to the extent of 5% occupancy of the third, "vacant" site.
23. See, for example: Knoth, W. H.; Domaille, P. J.; Harlow, R. L. lnorg. Chem. 1986, 25, 1577. Xin, F.; Pope, M. T. Organometallics 1994, 13, 4881
24. See, for example: Knoth, W. H.; Domaille, P. J.; Harlow, R. L. lnorg. Chem. 1986, 25, 1577. Xin, F.; Pope, M. T. Organometallics 1994, 13, 4881
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