Photochemistry of 2-azido-4,6-dichloro-s-triazine: Matrix isolation of a strained cyclic carbodiimide containing four nitrogen atoms in a seven-membered ring

Chemical Communications

Volumn , Issue 20, 1999, Pages 2113-2114

  Bucher, Götz ^a   Siegler, Fred ^b   Wolff, J Jens ^b  

^a RUHR UNIVERSITY BOCHUM   (Germany)

^b UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

2 AZIDO 4,6 DICHLOROTRIAZINE; AROMATIC HYDROCARBON; AZIDE; CYANAMIDE; UNCLASSIFIED DRUG;

ARTICLE; INFRARED SPECTROMETRY; PHOTOCHEMISTRY; ULTRAVIOLET SPECTROPHOTOMETRY;

EID: 0033592616     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a905971g     Document Type: Article

References (18)

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12. -1 (Ar, 10 K) 2168.9 (s), 1531.0 (vs), 1512.0 (vs), 1396.8 (s), 1295.8 (s), 1268.0 (s), 1187.6 (m), 1159.9 (m), 947.9 (w), 857.2 (m), 803.8 (w), 730.5 (vw).
13. The characterization of these final products is in progress; results will be published at a later time.
14. GAUSSIAN 98 software was used in the calculations.
15. -1 (ref. 18). The decrease in frequency in 3 reflects the decrease in bond energy induced by strain. A similar trend has been observed in the case of other cyclic carbodiimides (ref. 6).
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