Kinetic and mechanistic examination of NBu4[IrH2(CO)2I2] and NBu4[RhH2(CO)2I2] via para-hydrogen enhanced NMR spectroscopy

Chemical Communications

Volumn , Issue 10, 1999, Pages 889-890

  Hasnip, Sarah K ^a   Duckett, Simon B ^a   Taylor, Diana R ^b   Barlow, Graham K ^b   Taylor, Mike J ^b  

^a UNIVERSITY OF YORK   (United Kingdom)

^b BP EXPLORATION   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; IRIDIUM COMPLEX; RHODIUM COMPLEX;

ARTICLE; CHEMICAL REACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 0033591462     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a900961b     Document Type: Article

References (10)

1. C. R. Bowers and D. P. Weitekamp. J. Am. Chem. Soc., 1987, 109, 5541.
2. R. Eisenberg. Acc. Chem. Res., 1991, 24, 110.
3. J. N. Atterer and J. Bargon. Prog. Nucl. Magn. Reson. Spectrosc., 1997, 31, 293.
4. C. J. Sleigh and S. B. Duckett. Prog. Nucl. Magn. Reson. Spectrosc., 1999, 34, 71.
5. S. B. Duckett, C. L. Newell and R. Eisenberg. J. Am. Chem. Soc., 1994, 116, 10 548; S. B. Duckett and R. Eisenberg. J. Am. Chem. Soc., 1993, 115, 5292; S. B. Duckett, R. J. Mawby and M. G. Partridge. Chem. Commun., 1996, 383; P. D. Morran, S. A. Colebrooke, S. B. Duckett, J. A. B. Lohmann and R. Eisenberg. J. Chem. Soc., Dalton. Trans., 1998, 3363.
6. S. B. Duckett, C. L. Newell and R. Eisenberg. J. Am. Chem. Soc., 1994, 116, 10 548; S. B. Duckett and R. Eisenberg. J. Am. Chem. Soc., 1993, 115, 5292; S. B. Duckett, R. J. Mawby and M. G. Partridge. Chem. Commun., 1996, 383; P. D. Morran, S. A. Colebrooke, S. B. Duckett, J. A. B. Lohmann and R. Eisenberg. J. Chem. Soc., Dalton. Trans., 1998, 3363.
7. S. B. Duckett, C. L. Newell and R. Eisenberg. J. Am. Chem. Soc., 1994, 116, 10 548; S. B. Duckett and R. Eisenberg. J. Am. Chem. Soc., 1993, 115, 5292; S. B. Duckett, R. J. Mawby and M. G. Partridge. Chem. Commun., 1996, 383; P. D. Morran, S. A. Colebrooke, S. B. Duckett, J. A. B. Lohmann and R. Eisenberg. J. Chem. Soc., Dalton. Trans., 1998, 3363.
8. S. B. Duckett, C. L. Newell and R. Eisenberg. J. Am. Chem. Soc., 1994, 116, 10 548; S. B. Duckett and R. Eisenberg. J. Am. Chem. Soc., 1993, 115, 5292; S. B. Duckett, R. J. Mawby and M. G. Partridge. Chem. Commun., 1996, 383; P. D. Morran, S. A. Colebrooke, S. B. Duckett, J. A. B. Lohmann and R. Eisenberg. J. Chem. Soc., Dalton. Trans., 1998, 3363.
9. P. M. Maitlis, A. Haynes, G. J. Sunley and M. J. Howard, J. Chem. Soc., Dalton Trans., 1996, 2187.
10. 13CO labelled 1 is used both these resonances are split into a triplet. The hydride resonance attributable to 3c is observed when HI is added to 1.