메뉴 건너뛰기




Volumn 285, Issue 5431, 1999, Pages 1249-1253

Chemical 'double silts': Dynamical interference of photodissociation pathways in water

Author keywords

[No Author keywords available]

Indexed keywords

WATER;

EID: 0033587803     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.285.5431.1249     Document Type: Article
Times cited : (108)

References (23)
  • 6
    • 0001207125 scopus 로고
    • and references therein
    • J. Biesner et al., ibid. 91, 2901 (1989), and references therein.
    • (1989) J. Chem. Phys. , vol.91 , pp. 2901
    • Biesner, J.1
  • 7
    • 0001210107 scopus 로고    scopus 로고
    • 2O/Ar mixture. The detection axis, the molecular beam, and the photolysis laser beam are all perpendicular to each other in this experiment. The VUV laser serves as both the photolysis laser and the laser for Lyman-α excitation. The polarization of the 121.6 nm laser light can be changed by rotating the polarization of the 845-nm laser using a rotatable half-waveplate.
    • (1997) J. Chem. Phys. , vol.107 , pp. 6175
    • Schnieder, L.1    Seekamp-Rahn, K.2    Wrede, E.3    Welge, K.H.4
  • 12
    • 36549097171 scopus 로고
    • R. Schinke, V. Engel, V. Staemmler, ibid. 85, 4522 (1985). Classically, the smooth distribution of zero-point bending momentum at short H-OH distance becomes a smooth distribution of rotational motion of the OH(X) fragments at large H-OH distance. The equivalent quantum-mechanical model involves the mapping of the bending wave-function onto the product rotational wave-functions. But the latter are oscillatory functions of the angle between the OH bond and the recoil axis of the departing H-atom. Thus, the mapping of a bending wave-function which is restricted to a narrow range of angles can lead to an oscillation in the OH rotational population.
    • (1985) J. Chem. Phys. , vol.85 , pp. 4522
    • Schinke, R.1    Engel, V.2    Staemmler, V.3
  • 19
    • 0344073864 scopus 로고    scopus 로고
    • note
    • The dynamical calculations were carried out using the diabatic representation of Murrell et al. (17), and then transformed to the adiabatic representation for Figs. 4 and 5. This simplifies the treatment of geometric phase effects around conical intersections.
  • 20
    • 0345367316 scopus 로고    scopus 로고
    • in preparation
    • R. N. Dixon et al., in preparation.
    • Dixon, R.N.1
  • 23
    • 0344505085 scopus 로고    scopus 로고
    • note
    • R.N.D. is grateful to the Leverhulme Trust for the award of an Emeritus Research Fellowship. The experimental work was done at IAMS, supported by the National Science Council and the Academia Sinica of the Republic of China. X.Y. wishes to thank Y. T. Lee and K. Liu for helpful discussions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.