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1H NMR and COSY encapsulation experiments with 1,2-cyclohexanediols 12 and 13 strongly suggest that the cyclohexane skeleton is situated deep inside capsule 1, while the hydroxy groups are in the center and are directed towards each other. Most probably, they are involved in intermolecular hydrogen bonding with each other and the imide N-H functions of the capsule. For a related example, see: S. Hanessian, A. Gomtsyan, M. Simard, S. Roelens, J. Am. Chem. Soc. 1994, 116, 4495-4496.
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