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29
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85069277320
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note
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9. The sequence can be reversed with reduced overall yield by starting with the 4-O-acylation followed by acid promoted acetal hydrolysis and finally with 1-O-silylation.
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30
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0000844189
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31
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85069275714
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note
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11. 1,4-Butanediol was less useful as glycosyl acceptor in the glycosylation of 5.
-
-
-
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32
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85069284344
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note
-
13C NMR δ 170.5 (s), 96.7 (d), 68.7 (d), 66.8 (t), 65.8 (d), 45.3 (d), 29.4 (t), 26.2 (t), 22.4 (q), 16.3 (q).
-
-
-
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33
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85069280102
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note
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13. The dimerizations commonly furnished small amounts of cross-metathesis products obtained from the initially released styrene.
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