An icosahedral array of methyl groups supported by an aromatic borane scaffold: The [closo-B12(CH3)12]2- ion

Journal of the American Chemical Society

Volumn 121, Issue 23, 1999, Pages 5601-5602

  Peymann, Toralf ^a   Knobler, Carolyn B ^a   Hawthorne, M Frederick ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BORANE DERIVATIVE; CARBORANE DERIVATIVE; FULLERENE; METHYL GROUP;

ARTICLE; CHEMICAL STRUCTURE; METHYLATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 0033575055     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja990884q     Document Type: Article

References (13)

1. Lehn, J.-M. Supramolecular Chemistry, VCH: Weinheim, New York, 1995.
2. Strauss, S. H. Chem. Rev. 1993, 93, 927-942.
3. Friedmann, S. H.; DeCamp, D. L.; Sijbesma, R. P.; Srdanov, G.; Wudl, F.; Kenyon, G. L. J. Am. Chem. Soc. 1993, 115, 6506-6509.
4. Hirsch, A. The Chemistry of the Fullerenes, G. Thieme Verlag: Stuttgart, New York, 1994.
5. Jiang, W.; Knobler, C. B.; Hawthorne, M. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 1332-1334.
6. King, B. T.; Janousek, Z.; Grüner, B.; Trammell, M.; Noll, B. C.; Michl, J. J. Am. Chem. Soc. 1996, 118, 3313-3314.
7. Herzog, A.; Maderna, A.; Harakas, G. N.; Knobler, C. B.; Hawthorne, M. F. Chem. Eur. J. 1999, 5, 1212-1217.
8. Peymann, T.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1998, 37, 1544-1548.
9. w = 0.184; GOF = 1.04.
10. Wunderlich, J. A.; Lipscomb, W. N. J. Am. Chem. Soc. 1960, 82, 4427-4428.
11. Liu, S.; Lu, Y.; Kappes, M. M.; Ibers, J. A. Science 1991, 254, 408-410.
12. King, B. T.; Noll, B. C.; McKinley, A. J.; Michl, J. J. Am. Chem. Soc. 1996, 118, 10902-10903.
13. - was observed under FAB conditions as the parent molecular ion of 1.