Does molecular HNO3 adsorb onto sulfuric acid droplet surfaces?

Geophysical Research Letters

Volumn 26, Issue 24, 1999, Pages 3625-3628

  Donaldson, D J ^a   Anderson, Darren ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; COMPOSITION EFFECTS; DROP FORMATION; INTERFACIAL ENERGY; NITRIC ACID; SULFURIC ACID; SURFACE TENSION; UPPER ATMOSPHERE; SULFUR DETERMINATION;

HETEROGENEOUS ACTIVITY; MOLECULAR PARTITIONING;

ATMOSPHERIC AEROSOLS; NITRIC ACID;

ADSORPTION; ATMOSPHERIC CHEMISTRY; NITRIC ACID; SULFURIC ACID;

ACID CONCENTRATIONS; ACID WATERS; DROPLET SURFACES; EXPOSED TO; SULFURIC ACID SOLUTION; SURFACE TENSION MEASUREMENTS;

EID: 0033573510     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/1999GL010894     Document Type: Article

References (28)

1. 2 and HCl on nitric acid trihydrate at 202 K, J. Phys. Chem. 96, 7674-7679, 1992.
2. thEddition, Wiley-Interscience. New York, 1997.
3. 4 salt solutions on surface water molecules using sum frequency generation. J. Phys. Chem. B 103 2789-2795, 1999.
4. 4 binary systems, J. Phys. Chem. B 101, 10435-10441, 1997.
5. nd Edition, Academic Press, New York, 1958
6. Defay, R., I. Prigogine, A. Bellemans and D.H. Everett. Surface Tension and Adsorption, Longmans, London 1966
7. 3, J. Phys.Chem.A 103, 62-70, 1999.
8. 2 at the aqueous-air interface, J. Phys. Chem. 99, 9313-9315 , 1995.
9. 4 alcohols, acids and acetone, J. Phys.ChemA. 103, 871-876, 1999.
10. 2O solutions, Faraday Discuss. 100, 269-278, 1995.
11. 2O binary system, J. Phys. Chem. 100, 13696-13799, 1996.
12. Geiger, P.M., PhD dissertation, Georgetown University, 1999.
13. 2O solutions at low temperatures, J. Phys. Chem. 92, 6167-6170, 1988
14. 3 onto ice, NAT and frozen sulfuric acid, Geophys. Res. Lett. 19, 2063-2066, 1992.
15. Hanson, D.R., Surface-specific reactions on liquids, J. Phys. Chem B 101, 4998-5001, 1997.
16. 2O mixtures, J. Phys. Chem. A 102, 4794-4807, 1998.
17. Iraci, L.T., A.M. Middlebrook, M.A. Wilson and M.A. Tolbert, Growth of nitric acid hydrates on thin sulfuric acid films, Geophys. Res. Lett. 21, 867-870, 1994.
18. Iraci, L.T., T.J. Fortin and M.A. Tolbert, Dissolution of sulfuric acid tetrahydrate at low temperatures and subsequent growth of nitric acid trihydrate, J. Geophys. Res. D 103, 8491-8498, 1998.
19. Kolb, C.E. et al., Laboratory studies of heterogeneous atmospheric chemistry, in Advanced Series in Physical Chemistry, Vol. 3, Progress and Problems in Atmospheric Chemistry, J.R. Barker. Ed., World Scientific, Singapore, 1995.
20. 2O solutions, Geophys. Res. Lett. (companion piece).
21. st Edition; CRC Press; Boca Raton, 1990
22. Phillips, L.F., Surface concentrations and compound formation in aqueous sulfuric acid, Aust. J. Chem. 47, 91-99, 1994.
23. Raduge, C., V. Pflumio and Y.R. Shen, Surface vibrational spectroscopy of sulfuric acid-water mixtures at the liquid-vapor interface, Chem. Phys. Lett. 274, 140-144, 1997.
24. Sabinina, L. and L. Terpugow, Die oberflachenspannung des systems schwefelsaure-wasser, Z Physik. Chem. A173, 237-241, 1935.
25. 3 by aqueous sulfuric acid droplets, J. Phys. Chem. 95, 1684-1689, 1991.
26. 2O systems: incorporation of stratospheric acids into background sulfate aerosols, J. Phys. Chem. 97, 8541-8548, 1993.
27. 2, HCl and HOCl on liquid sulfuric acid surfaces, J. Phys. Chem. 98, 13563-13574, 1994.
28. 2O ternary solutions under stratospheric conditions, Geophys. Res. Lett. 22, 1493-1496, 1995.