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Volumn 1, Issue 22, 1999, Pages 5179-5188

The bundle theory for polymer crystallisation

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER;

EID: 0033571179     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/a905658k     Document Type: Article
Times cited : (44)

References (49)
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    • 0 In λ), i.e., the free energy difference per crystallised stem. We believe it reasonable that in reality η should be smaller than the value taken by us, and the number of bonds per stem, α, correspondingly larger (see also the discussion in Section 4).
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    • 21 Notice that, by contrast, the usual solvent-mediated attraction forces would not determine any intramolecular contraction in a very concentrated solution - nor, for that matter, even in the polymer bulk by extrapolation - because the energy of any interaction is taken to depend solely on the existence of the interatomic contact, with no reduction of configurational degrees of freedom.
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    • note
    • i being the number of stems in the ith bundle.
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