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Volumn 121, Issue 36, 1999, Pages 8385-8386

Inversion of configuration during the hydrolysis of D-1-S(p)-myo- inositol [17O]thiophosphate catalyzed by myo-inositol monophosphatase

Author keywords

[No Author keywords available]

Indexed keywords

INOSITOL PHOSPHATE;

EID: 0033568631     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991939r     Document Type: Article
Times cited : (10)

References (30)
  • 20
    • 0025726522 scopus 로고
    • (D/L)-1,2;4,5-Di-O-cyclohexylidene-myo-inositol was synthesized according to literature methods: Dreef, C. E.; Tulnman, R. J.; Lefeber, A. W. M. Tetrahedron 1991, 47, 4709. The assignment of the diastereomers was made by comparison with the product of phosphorylation of a sample of the resolved diol of known absolute configuration: Vacca, J. P.; deSolms, S. J.; Huff, J. R.; Billington, D. C.; Baker, R.; Kulagowski, J. J.; Maver, I. M. Tetrahedron 1989, 45, 5679; 1991, 47, 907 (corrigenda).
    • (1991) Tetrahedron , vol.47 , pp. 4709
    • Dreef, C.E.1    Tulnman, R.J.2    Lefeber, A.W.M.3
  • 21
    • 0024438459 scopus 로고
    • (D/L)-1,2;4,5-Di-O-cyclohexylidene-myo-inositol was synthesized according to literature methods: Dreef, C. E.; Tulnman, R. J.; Lefeber, A. W. M. Tetrahedron 1991, 47, 4709. The assignment of the diastereomers was made by comparison with the product of phosphorylation of a sample of the resolved diol of known absolute configuration: Vacca, J. P.; deSolms, S. J.; Huff, J. R.; Billington, D. C.; Baker, R.; Kulagowski, J. J.; Maver, I. M. Tetrahedron 1989, 45, 5679; 1991, 47, 907 (corrigenda).
    • (1989) Tetrahedron , vol.45 , pp. 5679
    • Vacca, J.P.1    DeSolms, S.J.2    Huff, J.R.3    Billington, D.C.4    Baker, R.5    Kulagowski, J.J.6    Maver, I.M.7
  • 22
    • 0026082598 scopus 로고
    • corrigenda
    • (D/L)-1,2;4,5-Di-O-cyclohexylidene-myo-inositol was synthesized according to literature methods: Dreef, C. E.; Tulnman, R. J.; Lefeber, A. W. M. Tetrahedron 1991, 47, 4709. The assignment of the diastereomers was made by comparison with the product of phosphorylation of a sample of the resolved diol of known absolute configuration: Vacca, J. P.; deSolms, S. J.; Huff, J. R.; Billington, D. C.; Baker, R.; Kulagowski, J. J.; Maver, I. M. Tetrahedron 1989, 45, 5679; 1991, 47, 907 (corrigenda).
    • (1991) Tetrahedron , vol.47 , pp. 907
  • 27
    • 0345392944 scopus 로고    scopus 로고
    • note
    • 16O. Using these values, the predicted ratio for the resonances from the trans ester (A:B:C) for inversion of configuration is 40.6:34.9:24.5, whereas for retention of configuration the ratios would be 40.6:24.5:34.9. The experimental ratios A:B:C of 40.5:33.5: 26 are in excellent agreement with complete inversion of configuration (the ratios for the cis esters are, of course, complementary).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.