Novel infinite three-dimensional networks with highly conjugated polynitrile ligands: Syntheses, crystal structures, and magnetic properties of [Cu{C{C(CN)2]3}(H2O)2](n) and [Cu{C[C(CN)2]3}(en)](n) (en = NH2CH2CH2NH2)

Angewandte Chemie - International Edition

Volumn 38, Issue 1-2, 1999, Pages 113-115

  Triki, Smaïl ^a   Sala Pala, Jean ^a   Decoster, Marc ^a   Molinié, Philippe ^b   Toupet, Loïc ^c  

^a UNIVERSITÉ DE BRETAGNE OCCIDENTALE   (France)

^b UNIVERSITÉ DE NANTES   (France)

^c UNIVERSITÉ DE RENNES 1   (France)

Author keywords

Copper; Magnetic properties; Metallacycles; Polymers; Structure elucidation

Indexed keywords

7,7,8,8 TETRACYANO 4 QUINODIMETHANE; CYANOCARBANION DERIVATIVE; CYANOCARBON DERIVATIVE; LIGAND; TETRACYANOETHYLENE; UNCLASSIFIED DRUG;

ARTICLE; CONJUGATION; CRYSTAL STRUCTURE; LIGAND BINDING; MOLECULAR INTERACTION; ORGANIC CHEMISTRY; PHYSICAL ACTIVITY; STRUCTURE ANALYSIS; THREE DIMENSIONAL IMAGING;

EID: 0033556019     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990115)38:1/2<113::AID-ANIE113>3.0.CO;2-9     Document Type: Article

References (21)

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11. D. A. Long, W. O. George. Spectrochim. Acta 1963, 19, 1717-1729; S. Sakanoue, N. Yasuoka, M. Kakudo, N. Kasai, Bull. Chem. Soc. Jpn. 1971, 44, 1-8; K. Nakamura, Y. Kai, N. Yasuoka, N. Kasai. Bull. Chem. Soc. Jpn. 1981, 54, 3300-3303; H. Yamochi, T. Tsuji, G. Saito, T. Suzuki, Synth. Met. 1988, 27, A479-A484; M. D. Ward, J. C. Calabrese, Organometallics 1989, 8, 593-602; J. S. Miller, D. A. Dixon, J. C. Calabrese, C. Vazquez, P. J. Krusic, M. D. Ward, E. Wasserman, R. L. Harlow, J. Am. Chem. Soc. 1990, 112, 381-398; H. Yamochi, T. Nakamura, G. Saito, T. Kikuchi, S. Sato, K. Nozawa, M. Kinoshita, T. Sugano, F. Wudl, Synth. Met. 1991, 42, 1741-1744.
12. D. A. Long, W. O. George. Spectrochim. Acta 1963, 19, 1717-1729; S. Sakanoue, N. Yasuoka, M. Kakudo, N. Kasai, Bull. Chem. Soc. Jpn. 1971, 44, 1-8; K. Nakamura, Y. Kai, N. Yasuoka, N. Kasai. Bull. Chem. Soc. Jpn. 1981, 54, 3300-3303; H. Yamochi, T. Tsuji, G. Saito, T. Suzuki, Synth. Met. 1988, 27, A479-A484; M. D. Ward, J. C. Calabrese, Organometallics 1989, 8, 593-602; J. S. Miller, D. A. Dixon, J. C. Calabrese, C. Vazquez, P. J. Krusic, M. D. Ward, E. Wasserman, R. L. Harlow, J. Am. Chem. Soc. 1990, 112, 381-398; H. Yamochi, T. Nakamura, G. Saito, T. Kikuchi, S. Sato, K. Nozawa, M. Kinoshita, T. Sugano, F. Wudl, Synth. Met. 1991, 42, 1741-1744.
13. D. A. Long, W. O. George. Spectrochim. Acta 1963, 19, 1717-1729; S. Sakanoue, N. Yasuoka, M. Kakudo, N. Kasai, Bull. Chem. Soc. Jpn. 1971, 44, 1-8; K. Nakamura, Y. Kai, N. Yasuoka, N. Kasai. Bull. Chem. Soc. Jpn. 1981, 54, 3300-3303; H. Yamochi, T. Tsuji, G. Saito, T. Suzuki, Synth. Met. 1988, 27, A479-A484; M. D. Ward, J. C. Calabrese, Organometallics 1989, 8, 593-602; J. S. Miller, D. A. Dixon, J. C. Calabrese, C. Vazquez, P. J. Krusic, M. D. Ward, E. Wasserman, R. L. Harlow, J. Am. Chem. Soc. 1990, 112, 381-398; H. Yamochi, T. Nakamura, G. Saito, T. Kikuchi, S. Sato, K. Nozawa, M. Kinoshita, T. Sugano, F. Wudl, Synth. Met. 1991, 42, 1741-1744.
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15. 3, and GOF = 1.29 for 3. Further details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666, on quoting the depository numbers CSD-408624 and -408625.
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18. 2/3
19. T. P. Nguyen, M. Giffard, P. Molinié, J. Chem. Phys. 1994, 100, 8340-8346.
20. 2 anion is easier as the potassium salt than as the barium salt and 2) problems that arise from the possible co-precipitation of the copper complex and barium sulfate are avoided.
21. 2 anion is easier as the potassium salt than as the barium salt and 2) problems that arise from the possible co-precipitation of the copper complex and barium sulfate are avoided.