Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl3-catalyzed oxidation of C-H bonds with tert-butyl hydroperoxide

Tetrahedron Letters

Volumn 40, Issue 20, 1999, Pages 3847-3850

  Merrigan, Steven R ^a   Le Gloahec, Valerie N ^a   Smith, Jason A ^a   Barton, Derek H R ^a   Singleton, Daniel A ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ISOTOPE; TERT BUTYL HYDROPEROXIDE;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL REACTION; OXIDATION; REACTION TIME;

EID: 0033553487     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00637-1     Document Type: Article

References (27)

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17. 2° was never better that ±23%.
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19. HD will usually be less that ≈2, this methodology can still give reasonably precise measurements.
20. IV' 'Gif' oxidation system only with no acetic acid present.
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