Methane-derived polyanionic synthons from bis(phenylthio)methane

Tetrahedron Letters

Volumn 40, Issue 46, 1999, Pages 8177-8180

  Foubelo, Francisco ^a   Gutiérrez, Ana ^a   Yus, Miguel ^a  

^a UNIVERSITY OF ALICANTE   (Spain)

Author keywords

1,3 Dienes; 1,3 Diols; Deprotonation; Lithiation; Thioacetals

Indexed keywords

ALKADIENE; ALLYL ALCOHOL; CARBONYL DERIVATIVE; LITHIUM DERIVATIVE; METHANE; POLYANION; SULFIDE;

ARTICLE; CATALYST; CHEMICAL MODIFICATION; ION EXCHANGE; PROTON TRANSPORT; REACTION ANALYSIS; SYNTHESIS;

EID: 0033550187     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01732-3     Document Type: Article

References (24)

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17. Previous paper from our laboratory using this methodology: Foubelo, F.; Gutiérrez, A.; Yus, M. Synthesis 1999, 503-514 (Feature article).
18. Foubelo, F.; Gutiérrez, A.; Yus, M. Tetrahedron Lett., preceding communication.
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23. (a) Secondary functionalised organolithium compounds are very unstable compounds, which suffer ß-elimination even at very low temperatures. See, for instance: Barluenga, J.; Villamaña, J.; Fañanàs, F. J.; Yus, M. J. Chem. Soc., Perkin Trans. I 1984, 2685-2692.
24. 13C NMR of the reaction crude.