Electrochemical synthesis of ethyl pentafluoroacetoacetate

Tetrahedron Letters

Volumn 40, Issue 11, 1999, Pages 2203-2204

  Stepanov, Andrei A ^a   Minyaeva, Tatyana V ^a   Martynov, Boris I ^b  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b STATE RESEARCH INSTITUTE OF ORGANIC CHEMISTRY AND TECHNOLOGY   (Russian Federation)

Author keywords

Electrochemistry; Fluorine and compounds; Keto acids and derivatives

Indexed keywords

ACETAL DERIVATIVE; ACETOACETIC ACID DERIVATIVE; TRIFLUOROACETIC ACID; TRIMETHYLSILYL DERIVATIVE;

ARTICLE; CHEMICAL REACTION; ELECTROCHEMICAL ANALYSIS; HYDROLYSIS; SYNTHESIS;

EID: 0033548649     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00170-7     Document Type: Article

References (10)

1. McBee, E. T.; Pierce, O. R.; Kilbourne, H. W.; Wilson, E. R. J. Am. Chem. Soc. 1953; 75: 3152 - 153
2. McBee, E. T.; Pierce, O. R.; Kilbourne, H. W.; Baron, J. A. J. Am. Chem. Soc. 1953; 75: 4090 - 4091
3. Mayranovsky, V. G.; Ponomarev, A. M. Zh. Obsch. Khim. 1977; 47: 2343 -46.
4. 2Et were correspondingly: -2.58, -2.37, -1.96 V.
5. -4.
6. The possibility of the initial TMSC1 reduction was not taken into account because of it's high reduction potential: Martynov, B.I.; Stepanov, A.A. J. Fluor. Chem. 1997; 85: 127 - 8
7. Kitagawa, O; Taguchi, T.; Kobayashi, Y. Tetrahedron Lett. 1988; 29: 1803 - 1806
8. 3COOH is 46.4, s) and ethyl difluoroacetate formation by acidic hydrolysis.
9. 4Si: C, 39.05; H, 5.66; F, 28.08; Si, 8.30%.
10. 2: C, 32.74; H, 2.29; F, 43.16%.