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Volumn 121, Issue 31, 1999, Pages 7274-7275

The one-electron oxidation of an azazirconacyclobutene in the presence of B(C6F5)3 [7]

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ANALYSIS; ELECTRON; LETTER; MATHEMATICAL ANALYSIS; OXIDATION; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 0033546731     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja984290j     Document Type: Letter
Times cited : (50)

References (35)
  • 7
    • 0345329676 scopus 로고    scopus 로고
    • note
    • 7) limit cases, respectively. We prefer the terms large hyperfine and small hyperfine because there is only one k for exchange.
  • 10
    • 0345329674 scopus 로고    scopus 로고
    • note
    • 3 increases with time, along with slow formation of products that are diamagnetic but have not been identified.
  • 11
    • 0344035719 scopus 로고    scopus 로고
    • note
    • +•.
  • 14
    • 0344428032 scopus 로고    scopus 로고
    • note
    • 3 solutions (∼ 12 mM) to solutions of 2 (50 mM) varies between 5 and 25 Hz, whereas the broadening produced by 150 μM of ferricinium (enough to oxidize only 0.3% of the 2) is 44 Hz.
  • 19
    • 0344428030 scopus 로고    scopus 로고
    • note
    • F-F = 18.4).
  • 20
    • 0345722637 scopus 로고    scopus 로고
    • note
    • 3 on cobaltocene (before formation of the charged intermediate), and it is possible that reaction 6 gives rise to a radical anion at some stage.
  • 29
    • 0001447240 scopus 로고
    • 3 (19 NMR). These reactions were not noticeably exothermic, but extreme caution should be exercised in the reaction of perfluorinated organics with alkali metals (see the Caution in Marsella, J. A.; Gilicinski, A. G.; Coughlin, A. M.; Pez, G. P. J. Org. Chem. 1992, 57, 2856-2860).
    • (1992) J. Org. Chem. , vol.57 , pp. 2856-2860
    • Marsella, J.A.1    Gilicinski, A.G.2    Coughlin, A.M.3    Pez, G.P.4
  • 35
    • 33646508960 scopus 로고
    • and references therein
    • Bock, H.; Kaim, W. Acc. Chem. Res. 1982, 15, 9-17 and references therein.
    • (1982) Acc. Chem. Res. , vol.15 , pp. 9-17
    • Bock, H.1    Kaim, W.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.