α-(acyloxy)dialkylnitrosamines: Effects of structure on the formation of N-nitrosiminium ions and a predicted change in mechanism

Journal of the American Chemical Society

Volumn 121, Issue 9, 1999, Pages 1826-1833

  Cai, Hongliang ^a   Fishbein, James C ^a  

^a WAKE FOREST UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

NITROSAMINE;

AQUEOUS SOLUTION; ARTICLE; CONJUGATION; DECOMPOSITION; REACTION ANALYSIS; STEREOSPECIFICITY;

EID: 0033541159     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9833218     Document Type: Article

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45. 2 substituent has a single hydrogen atom that can stabilize the developing carbocation by hyperconjugation while those in Figure 3 have two; however, this means that the rate constant for 33 actually deviates by more than +3 log units from the appropriate correlation.
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