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0001690226
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For a report of the reaction of triplet carbon with benzene in crossed beams experiment, see: Kaiser, R. I.; Hahndorf, I.; Haung, L. C. L.; Lee, Y. T.; Bettinger, H. F.; Schleyer, P. v. R.; Schaefer, H. F., III; Schreiner, P. R. J. Chem. Phys. 1999, 110, 6091.
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0001938664
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For reviews of the chemistry of atomic carbon, see: (a) Skell, P. S.; Havel, J. J.; McGlinchey, M. J. Acc. Chem. Res. 1973, 6, 97. (b) MacKay, C. In Carbenes; Moss, R. A., Jones, M., Jr., Eds.; Wiley-Interscience: New York, 1975; Vol. II, pp 1-42. (c) Shevlin, P. B. In Reactive Intermediates; Abramovitch, R. A., Ed.; Plenum Press: New York, 1980; Vol. I, pp 1-36.
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0003128343
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Moss, R. A., Jones, M., Jr., Eds.; Wiley-Interscience: New York
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For reviews of the chemistry of atomic carbon, see: (a) Skell, P. S.; Havel, J. J.; McGlinchey, M. J. Acc. Chem. Res. 1973, 6, 97. (b) MacKay, C. In Carbenes; Moss, R. A., Jones, M., Jr., Eds.; Wiley-Interscience: New York, 1975; Vol. II, pp 1-42. (c) Shevlin, P. B. In Reactive Intermediates; Abramovitch, R. A., Ed.; Plenum Press: New York, 1980; Vol. I, pp 1-36.
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Abramovitch, R. A., Ed.; Plenum Press: New York
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Shevlin, P.B.1
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7
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84920351433
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note
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The experimental setup is described in ref 1. Carbon atoms and substrate were co-condensed at 77 K, and products were anaylzed by GC, GC/MS, and NMR.
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-
-
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10
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13044298168
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Platz, M. S., Ed.; Plenum: New York, and references cited
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Platz, M.S.1
Maloney, V.M.2
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0030978160
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84920362068
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note
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11
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15
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0030949567
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Poutsma, J. C.; Nash, J. J.; Paulino, J. A.; Squires, R. R. J. Am. Chem. Soc. 1997, 119, 4686.
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Deoxygenation of aryl aldehydes is known to generate chemically activated carbenes: Rahman, M.; Shevlin, P. B. Tetrahedron Lett. 1985, 26, 2959.
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36849137629
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D > 1 for the rearrangement of 1 to 4 was calculated using the method of Bigeleisen and Mayer: Bigeleisen, J.; Mayer, M. G. J. Chem. Phys. 1947, 15, 261. The calculations used the program QUIVER (Saunders, M.; Laidig, K. E.; Wolfsberg, M. J. Am. Chem. Soc. 1989, 111, 8989).
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Mayer, M.G.2
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0024841752
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D > 1 for the rearrangement of 1 to 4 was calculated using the method of Bigeleisen and Mayer: Bigeleisen, J.; Mayer, M. G. J. Chem. Phys. 1947, 15, 261. The calculations used the program QUIVER (Saunders, M.; Laidig, K. E.; Wolfsberg, M. J. Am. Chem. Soc. 1989, 111, 8989).
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84920354803
-
-
note
-
D for this step would be small.
-
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-
22
-
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84920341590
-
-
note
-
8 compounds in the GC/MS.
-
-
-
-
23
-
-
84920342137
-
-
note
-
8 on THF yields 4:(5 + 6) = 3.70), isotope effects in the presence and absence of 2-butene cannot be directly compared.
-
-
-
-
24
-
-
84920360388
-
-
note
-
2. Increasing this pressure increases the ratio of (7 + 8):(5 + 6).
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25
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0004344770
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