Reversible carbon-carbon bond heterolysis of a hydrocarbon derived from tert-butylfulleride ion and tricyclopropylcyclopropenylium ion

Journal of Organic Chemistry

Volumn 64, Issue 1, 1999, Pages 2-3

  Kitagawa, Toshikazu ^a   Tanaka, Toru ^a   Murakita, Hideyuki ^a   Takeuchi, Ken'ichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CYCLOPROPANE DERIVATIVE; FULLERENE DERIVATIVE; HYDROCARBON; SOLVENT;

ARTICLE; CYCLIC POTENTIOMETRY; LYSIS; MASS SPECTROMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 0033534671     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo981503e     Document Type: Article

References (20)

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8. 4, was removed by extraction with carbon disulfide followed by filtration through a 0.45 μm Teflon membrane filter. The obtained product 4 was essentially pure and was used without further purification for spectroscopic characterization and related studies.
9. max (ε) 213 (131 000), 257 (10 100), 327sh (29 900), 446 (5920) with end absorption to 750 nm. Details are given in the Supporting Information.
10. Irradiation of the tert-butyl protons led to significant enhancement (21, 17, and 17%) of the three methine-proton signals.
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17. max 995 nm, ε 2400, ref 3).
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