An efficient method for cleavage of epoxides with aromatic amines

Journal of Organic Chemistry

Volumn 64, Issue 1, 1999, Pages 287-289

  Sekar, Govindasamy ^a   Singh, Vinod K ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY KANPUR   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AMINOALCOHOL; AROMATIC AMINE; COPPER; EPOXIDE; TIN;

ARTICLE; CATALYSIS; CHEMICAL REACTION; STEREOCHEMISTRY;

EID: 0033534609     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo981196c     Document Type: Article

References (24)

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4. 2).
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17. (a) Sekar, G.; DattaGupta, A.; Singh, V. K. J. Org. Chem. 1998, 63, 2961.
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20. There are two reports (ref 2a,d) in the literature for a similar kind of preference for aromatic amines in the opening of epoxides; however, the yield was modest even for activated aromatic amines and the reaction failed with deactivated aromatic amines such as p-nitroaniline.
21. Brown, D. W.; Ninan, A.; Sainsbury, M. Synthesis 1997, 895.
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