Enantioselective electrocatalytic oxidation of racemic amines using a chiral 1-azaspiro[5.5]undecane N-oxyl radical

Chemical Communications

Volumn , Issue 19, 1999, Pages 1983-1984

  Kashiwagi, Yoshitomo ^a   Kurashima, Futoshi ^a   Kikuchi, Chikara ^a   Anzai, Jun Ichi ^a   Osa, Tetsuo ^a   Bobbitt, James M ^b  

^a TOHOKU UNIVERSITY   (Japan)

^b UNIVERSITY OF CONNECTICUT   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE; RADICAL;

ARTICLE; CHIRALITY; ELECTROLYSIS; OXIDATION; TIME;

EID: 0033533767     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a905894j     Document Type: Article

References (10)

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10. S = ln[(1 - C)(1 - ee)]/ln[(1 - C)(1 + ee)], where ee is the fractional enantiomeric excess and C is the conversion. For a discussion of kinetic resolutions see: H. B. Kagan and J. C. Fiaund, Top. Stereochem., 1988, 18, 249.