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85034131671
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note
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Varied regioselectivity was observed with trichloroacetimidates derived from allylic alcohols. For example, etherification of 1a with the trichloroacetimidate of crotyl alcohol gave a separable mixture of 2a (67%)- and 2b (25%), while reaction of 1b with the trichloroacetimidate of cinnamyl alcohol gave 2d, exclusively,
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29
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85034139613
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note
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All reactions were run with 3.0 equiv of CsF in DMF at room temperature over 16 h. See Supporting Information for more details.
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