Palladium-catalysed asymmetric allylic alkylation using new chiral phosphinite-nitrogen ligands derived from D-glucosamine

Chemical Communications

Volumn , Issue 5, 1999, Pages 415-416

  Yonehara, Koji ^a   Hashizume, Tomohiro ^a   Mori, Kenji ^a   Obe, Kouichi ^a   Uemura, Sakae ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; GLUCOSAMINE; LIGAND; NITROGEN; PALLADIUM; PHOSPHINIC ACID DERIVATIVE;

ALKYLATION; ARTICLE; CATALYST; CHIRALITY; ENANTIOMER; ORGANIC CHEMISTRY;

EID: 0033531439     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a810041a     Document Type: Article

References (18)

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12. The phosphorous atom is a better π-acceptor than the nitrogen atom in π-allyl-palladium complexes bearing a P-N bidentate ligand. For examples, see: B. Åkermark, B. Krakenberger, S. Hansson and A. Vitagliano, Organometallics, 1987, 6, 620; P. E. Blöchl and A. Togni, Organometallics, 1996, 15, 4125; E. Peña-Cabrera, P.-O. Norrby, M. Sjögren, A. Vitagliano, V. De Felice, J. Oslob, S. Ishii, D. O'Neill, B. Ākermark and P. Helquist, J. Am. Chem. Soc., 1996, 118, 4299; H. Steinhagen, M. Reggelin and G. Helmchen, Angew. Chem., Int. Ed. Engl., 1997, 36, 2108.
13. The phosphorous atom is a better π-acceptor than the nitrogen atom in π-allyl-palladium complexes bearing a P-N bidentate ligand. For examples, see: B. Åkermark, B. Krakenberger, S. Hansson and A. Vitagliano, Organometallics, 1987, 6, 620; P. E. Blöchl and A. Togni, Organometallics, 1996, 15, 4125; E. Peña-Cabrera, P.-O. Norrby, M. Sjögren, A. Vitagliano, V. De Felice, J. Oslob, S. Ishii, D. O'Neill, B. Ākermark and P. Helquist, J. Am. Chem. Soc., 1996, 118, 4299; H. Steinhagen, M. Reggelin and G. Helmchen, Angew. Chem., Int. Ed. Engl., 1997, 36, 2108.
14. The phosphorous atom is a better π-acceptor than the nitrogen atom in π-allyl-palladium complexes bearing a P-N bidentate ligand. For examples, see: B. Åkermark, B. Krakenberger, S. Hansson and A. Vitagliano, Organometallics, 1987, 6, 620; P. E. Blöchl and A. Togni, Organometallics, 1996, 15, 4125; E. Peña-Cabrera, P.-O. Norrby, M. Sjögren, A. Vitagliano, V. De Felice, J. Oslob, S. Ishii, D. O'Neill, B. Ākermark and P. Helquist, J. Am. Chem. Soc., 1996, 118, 4299; H. Steinhagen, M. Reggelin and G. Helmchen, Angew. Chem., Int. Ed. Engl., 1997, 36, 2108.
15. The phosphorous atom is a better π-acceptor than the nitrogen atom in π-allyl-palladium complexes bearing a P-N bidentate ligand. For examples, see: B. Åkermark, B. Krakenberger, S. Hansson and A. Vitagliano, Organometallics, 1987, 6, 620; P. E. Blöchl and A. Togni, Organometallics, 1996, 15, 4125; E. Peña-Cabrera, P.-O. Norrby, M. Sjögren, A. Vitagliano, V. De Felice, J. Oslob, S. Ishii, D. O'Neill, B. Ākermark and P. Helquist, J. Am. Chem. Soc., 1996, 118, 4299; H. Steinhagen, M. Reggelin and G. Helmchen, Angew. Chem., Int. Ed. Engl., 1997, 36, 2108.
16. Some imino-phosphinite ligands and their application to other asymmetric reactions have been reported: C. G. Arena, F. Nicolo, D. Drommi, G. Brunò and F. Faraone, J. Chem. Soc., Chem. Commun., 1994, 2251; R. Sablong, C. Newton, P. Dierkes and J. A. Osborn, Tetrahedron Lett., 1996, 37, 4933; R. Sablong and J. A. Osborn,Tetrahedron Lett., 1996, 37, 4937.
17. Some imino-phosphinite ligands and their application to other asymmetric reactions have been reported: C. G. Arena, F. Nicolo, D. Drommi, G. Brunò and F. Faraone, J. Chem. Soc., Chem. Commun., 1994, 2251; R. Sablong, C. Newton, P. Dierkes and J. A. Osborn, Tetrahedron Lett., 1996, 37, 4933; R. Sablong and J. A. Osborn,Tetrahedron Lett., 1996, 37, 4937.
18. Some imino-phosphinite ligands and their application to other asymmetric reactions have been reported: C. G. Arena, F. Nicolo, D. Drommi, G. Brunò and F. Faraone, J. Chem. Soc., Chem. Commun., 1994, 2251; R. Sablong, C. Newton, P. Dierkes and J. A. Osborn, Tetrahedron Lett., 1996, 37, 4933; R. Sablong and J. A. Osborn,Tetrahedron Lett., 1996, 37, 4937.