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Volumn 64, Issue 5, 1999, Pages 1585-1590

Alkali metal alkoxide clusters: Convenient catalysts for the synthesis of methylphosphonates

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METAL; METHYLPHOSPHONIC ACID;

EID: 0033525639     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9820521     Document Type: Article
Times cited : (11)

References (26)
  • 11
    • 4243926603 scopus 로고
    • Georg Thieme Verlag: Stuttgart, Germany
    • (c) Müller, E. Methoden Der Organischen Chemie; Georg Thieme Verlag: Stuttgart, Germany, 1963; Vol. 12, pp 387-420.
    • (1963) Methoden Der Organischen Chemie , vol.12 , pp. 387-420
    • Müller, E.1
  • 15
    • 0344007187 scopus 로고    scopus 로고
    • note
    • Dimethyl phenylphosphonate was found to behave similarly, in fact, giving slightly higher rates than DMMP.
  • 16
    • 0344438472 scopus 로고    scopus 로고
    • note
    • This estimate does not take into account the extra turnovers required to convert methyl ethyl methylphosphonate to diethyl methylphosphonate.
  • 17
    • 0344870308 scopus 로고    scopus 로고
    • note
    • Some THF was necessary for reactivity as reactions carried out in neat tBuOAc were sluggish.
  • 18
    • 0003942864 scopus 로고
    • John Wiley & Sons: New York, Chapter 10
    • Since IMMP is chiral, it therefore has an additional contribution to its entropy equal to R In 2, the entropy of mixing. See: Eliel, E. L.; Wilen, S. H. Stereochemistry of Organic Compounds; John Wiley & Sons: New York, 1994; Chapter 10, p 601.
    • (1994) Stereochemistry of Organic Compounds , pp. 601
    • Eliel, E.L.1    Wilen, S.H.2
  • 22
    • 84981790880 scopus 로고
    • Since NaOMe is an insoluble sheetlike material, the catalyst is most reasonably in a solubilized form: (a) Weiss, von E.; Alsdorf, H. Z. Anorg. Chem. 1970, 372, 206-213.
    • (1970) Z. Anorg. Chem. , vol.372 , pp. 206-213
    • Von Weiss, E.1    Alsdorf, H.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.